Issue 20, 2001

Synthesis of dihydrobenzazaphospholeligandsvia an intramolecular cyclisation reaction

Abstract

A novel intramolecular cyclisation reaction of 1,3,2-oxazaphospholidines has been employed for the diastereoselective synthesis of chiral, non-racemic dihydrobenzazaphosphole ligands. The new ligands have been employed in enantioselective palladium-catalysed allylic substitution reactions.

Graphical abstract: Synthesis of dihydrobenzazaphosphole ligands via an intramolecular cyclisation reaction

Supplementary files

Article information

Article type
Paper
Submitted
21 Jun 2001
Accepted
21 Aug 2001
First published
21 Sep 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 2588-2594

Synthesis of dihydrobenzazaphosphole ligands via an intramolecular cyclisation reaction

W. Leung, S. Cosway, R. H. V. Jones, H. McCann and M. Wills, J. Chem. Soc., Perkin Trans. 1, 2001, 2588 DOI: 10.1039/B105495N

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