Hot Article: High field-emitting nanobelts
16 August 2007
A non-catalytic and template-free method has been developed to form quasi-aligned zinc-sulfur (ZnS) nanobelts, by scientists in Japan.
It is known that ZnS has a wide bandgap and thus is a very good semiconductor, and is subsequently an important material in the electronics industry. Usually ZnS nanostructures are synthesized by randomly placing them on to the substrates.
Xiaosheng Fang and co-workers from the National Institute for Materials Science in Ibaraki, have reported ZnS nanobelts with a different structure and shape from those previously reported. These nanobelts were aligned on a micro/macroscopic scale and also displayed similar crystallographic orientation to their growth axes.

Furthermore, field-emission (FE) measurements were carried out on these nanobelts and the observed field emission properties surpassed that of some already pre-existing FE materials.
'The measured emission current densities reached ~14.6 mA/cm2 at a macroscopic field of 5.5 V/mm, which is more than 20 times of that in randomly oriented ZnS nanobelts' said Fang.
This new method shows that growing a large area of orientation-ordered ZnS nanobelts, which grow uniformly and aligned, enhances their field-emitting ability. In the future, this material could be utilised in novel field emitters, luminescence and electronic devices, as well as in the development of sensors.
Emma Shiells
Link to journal article
Crystal orientation-ordered ZnS nanobelt quasi-arrays and their enhanced field-emission
Xiaosheng Fang, Yoshio Bando, Changhui Ye and Dmitri Golberg, Chem. Commun., 2007, 3048
DOI: 10.1039/b705410f
