Chemical Science 2041-6520 Royal Society of Chemistry Front cover 10.1039/c2sc90014a AuthorAnonymous 2012 3 5 1345 1345 Abstract HTML PDF other

Chemical Science 2041-6520 Royal Society of Chemistry Inside front cover 10.1039/c2sc90015g AuthorAnonymous 2012 3 5 1346 1346 Abstract HTML PDF other

Chemical Science 2041-6520 Royal Society of Chemistry Contents list 10.1039/c2sc90017c AuthorAnonymous 2012 3 5 1347 1362 Abstract HTML PDF other

Chemical Science 2041-6520 Royal Society of Chemistry Biological stimuli and biomolecules in the assembly and manipulation of nanoscale polymeric particles 10.1039/c2sc00857b Randolph Lyndsay M. Chien Miao-Ping Gianneschi Nathan C. 2012 3 5 1363 1380 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Hydrogen bonds with fluorine. Studies in solution, in gas phase and by computations, conflicting conclusions from crystallographic analyses 10.1039/c2sc00764a Schneider Hans-Jörg 2012 3 5 1381 1394 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Metallosupramolecular amphiphilic π-systems 10.1039/c2sc01101h Muñoz María José Mayoral Fernández Gustavo 2012 3 5 1395 1398 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Substituent effects in a series of 1,7-C₆₀(R_F)₂ compounds (R_F = CF₃, C₂F₅, <i>n</i>-C₃F₇, <i>i</i>-C₃F₇, <i>n</i>-C₄F₉, <i>s</i>-C₄F₉, <i>n</i>-C₈F₁₇): electron affinities, reduction potentials and <i>E</i>(LUMO) values are not always correlated 10.1039/c2sc01133f Kuvychko Igor V. Whitaker James B. Larson Bryon W. Folsom Travis C. Shustova Natalia B. Avdoshenko Stanislav M. Chen Yu-Sheng Wen Hui Wang Xue-Bin Dunsch Lothar Popov Alexey A. Boltalina Olga V. Strauss Steven H. 2012 3 5 1399 1407 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Potent inhibition of ice recrystallization by low molecular weight carbohydrate-based surfactants and hydrogelators 10.1039/c2sc00885h Capicciotti Chantelle J. Leclère Mathieu Perras Frédéric A. Bryce David L. Paulin Hilary Harden James Liu Yun Ben Robert N. 2012 3 5 1408 1416 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Novel self-assembled dynamic [2]catenanes interlocked by the quadruple hydrogen bonding ureidopyrimidinone motif 10.1039/c2sc01004f Xiao Tangxin Li Shao-Lu Zhang Yajie Lin Chen Hu Bingjie Guan Xinchao Yu Yihua Jiang Juli Wang Leyong 2012 3 5 1417 1421 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Asymmetric C(sp³)-H/C(Ar) coupling reactions. Highly <i>enantio</i>-enriched indolines <i>via</i> regiodivergent reaction of a racemic mixture 10.1039/c2sc20111a Katayev Dmitry Nakanishi Masafumi Bürgi Thomas Kündig E. Peter 2012 3 5 1422 1425 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Chemical control of octahedral tilting and off-axis A cation displacement allows ferroelectric switching in a bismuth-based perovskite 10.1039/c2sc01115h Dolgos M. Adem U. Wan X. Xu Z. Bell A. J. Comyn T. P. Stevenson T. Bennett J. Claridge J. B. Rosseinsky M. J. 2012 3 5 1426 1435 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Tunable transmembrane chloride transport by bis-indolylureas 10.1039/c2sc20041d Haynes Cally J. E. Moore Stephen J. Hiscock Jennifer R. Marques Igor Costa Paulo J. Félix Vítor Gale Philip A. 2012 3 5 1436 1444 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Morphology, wettability and photomicropatterning of superhydrophobic surface with high adhesive force by crystal growth of a photochromic diarylethene 10.1039/c2sc20051a Kitagawa Daichi Kobatake Seiya 2012 3 5 1445 1449 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Two-, three- and four-component coupling to form isoquinolones based on directed metalation 10.1039/c2sc20102j Antczak Monika I. Ready Joseph M. 2012 3 5 1450 1454 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry The hidden force opposing ice compression 10.1039/c2sc20066j Sun Chang Q Zhang Xi Zheng Weitao 2012 3 5 1455 1460 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Heteroarene-fused boroles: what governs the antiaromaticity and Lewis acidity of the borole skeleton? 10.1039/c2sc20100c Iida Azusa Sekioka Anna Yamaguchi Shigehiro 2012 3 5 1461 1466 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Restricted access boronate affinity porous monolith as a protein A mimetic for the specific capture of immunoglobulin G 10.1039/c2sc20125a Liu Yunchun Lu Yue Liu Zhen 2012 3 5 1467 1471 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Immobilizing NIR absorbing azulenocyanines onto single wall carbon nanotubes—from charge transfer to photovoltaics 10.1039/c2sc20071f Ince Mine Bartelmess Juergen Kiessling Daniel Dirian Konstantin Martínez-Díaz M. Victoria Torres Tomás Guldi Dirk M. 2012 3 5 1472 1480 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Layered double hydroxide (LDH)–organic hybrids as precursors for low-temperature chemical synthesis of carbon nanoforms 10.1039/c2sc01064j Abellán Gonzalo Coronado Eugenio Martí-Gastaldo Carlos Ribera Antonio Sánchez-Royo Juan F. 2012 3 5 1481 1485 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Densely substituted unnatural l- and d-prolines as catalysts for highly enantioselective stereodivergent (3 + 2) cycloadditions and aldol reactions 10.1039/c2sc20199b Conde Egoitz Bello Davide Cózar Abel de Sánchez Mirian Vázquez Miguel A. Cossío Fernando P. 2012 3 5 1486 1491 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Self-organizing surface-initiated polymerization of perylenediimides on indium tin oxides 10.1039/c2sc01047j Charbonnaz Pierre Sakai Naomi Matile Stefan 2012 3 5 1492 1496 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Estimating chemical reactivity and cross-influence from collective chemical knowledge 10.1039/c2sc00011c Soh Siowling Wei Yanhu Kowalczyk Bartlomiej Gothard Chris M. Baytekin Bilge Gothard Nosheen Grzybowski Bartosz A. 2012 3 5 1497 1502 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Mutational Locally Enhanced Sampling (MULES) for quantitative prediction of the effects of mutations at protein–protein interfaces 10.1039/c2sc00895e Bradshaw Richard T. Aronica Pietro G. A. Tate Edward W. Leatherbarrow Robin J. Gould Ian R. 2012 3 5 1503 1511 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Development of a robust supramolecular method to prepare well-defined nanofibrils from conjugated molecules 10.1039/c2sc00977c Tian Liangfei Szilluweit Ruth Marty Roman Bertschi Louis Zerson Mario Spitzner Eike-Christian Magerle Robert Frauenrath Holger 2012 3 5 1512 1521 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Acid/base controlled size modulation of capsular phosphates, hydroxide encapsulation, quantitative and clean extraction of sulfate with carbonate capsules of a tripodal urea receptor 10.1039/c2sc00021k Akhuli Bidyut Ravikumar I. Ghosh Pradyut 2012 3 5 1522 1530 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Kinetics and mechanism of metal–organic framework thin film growth: systematic investigation of HKUST-1 deposition on QCM electrodes 10.1039/c2sc20065a Stavila Vitalie Volponi Joanne Katzenmeyer Aaron M. Dixon Matthew C. Allendorf Mark D. 2012 3 5 1531 1540 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Engineering conjugation in <i>para</i>-phenylene-bridged porphyrin tapes 10.1039/c2sc00023g Pawlicki Miłosz Morisue Mitsuhiko Davis Nicola K. S. McLean Daniel G. Haley Joy E. Beuerman Erich Drobizhev Mikhail Rebane Aleksander Thompson Amber L. Pascu Sofia I. Accorsi Gianluca Armaroli Nicola Anderson Harry L. 2012 3 5 1541 1547 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Rare-earth monocarbonyls MCO: comprehensive infrared observations and a transparent theoretical interpretation for M = Sc; Y; La–Lu 10.1039/c2sc00998f Xu Wenhua Jin Xi Chen Mohua Pyykkö Pekka Zhou Mingfei Li Jun 2012 3 5 1548 1554 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Expedient construction of small molecule macroarrays <i>via</i> sequential palladium- and copper-mediated reactions and their <i>ex situ</i> biological testing 10.1039/c2sc01089e Frei Reto Breitbach Anthony S. Blackwell Helen E. 2012 3 5 1555 1561 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Effect of ligand electronic properties on precatalyst initiation and propagation in Ni-catalyzed cross-coupling polymerizations 10.1039/c2sc00005a Lee Se Ryeon Bryan Zachary J. Wagner Anna M. McNeil Anne J. 2012 3 5 1562 1566 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Developing the mechanism of dioxygen reduction catalyzed by multicopper oxidases using protein film electrochemistry 10.1039/c2sc00632d Cracknell James A. Blanford Christopher F. 2012 3 5 1567 1581 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Osmium(vi) nitrido complexes bearing azole heterocycles: a new class of antitumor agents 10.1039/c2sc01031c Ni Wen-Xiu Man Wai-Lun Yiu Shek-Man Ho Man Cheung Myra Ting-Wai Ko Chi-Chiu Che Chi-Ming Lam Yun-Wah Lau Tai-Chu 2012 3 5 1582 1588 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Rh₂(<i>S</i>-PTTL)₃TPA—a mixed-ligand dirhodium(ii) catalyst for enantioselective reactions of α-alkyl-α-diazoesters 10.1039/c2sc01134d Boruta David T. Dmitrenko Olga Yap Glenn P. A. Fox Joseph M. 2012 3 5 1589 1593 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry pH-induced mechanistic changeover from hydroxyl radicals to iron(iv) in the Fenton reaction 10.1039/c2sc20099f Bataineh Hajem Pestovsky Oleg Bakac Andreja 2012 3 5 1594 1599 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Oxygen activation in extradiol catecholate dioxygenases – a density functional study 10.1039/c2sc00754a Christian Gemma J. Ye Shengfa Neese Frank 2012 3 5 1600 1611 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Visible-light-mediated photochemistry: accelerating Ru(bpy)₃²⁺-catalyzed reactions in continuous flow 10.1039/c2sc01016j Bou-Hamdan Farhan R. Seeberger Peter H. 2012 3 5 1612 1616 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Streamlined access to conjugation-ready glycans by automated synthesis 10.1039/c2sc00940d Kröck Lenz Esposito Davide Castagner Bastien Wang Cheng-Chung Bindschädler Pascal Seeberger Peter H. 2012 3 5 1617 1622 Abstract HTML PDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Molecular scaffolds with remote directing groups for selective palladium-catalyzed C–H bond functionalizations 10.1039/c2sc20176c Stache Erin E. Seizert Curtis A. Ferreira Eric M. 2012 3 5 1623 1628 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Remarkably high-temperature spin transition exhibited by new 2D metal–organic frameworks 10.1039/c2sc00924b Bao Xin Guo Peng-Hu Liu Wei Tucek Jiri Zhang Wei-Xiong Leng Ji-Dong Chen Xiao-Ming Gural'skiy Il'ya Salmon Lionel Bousseksou Azzedine Tong Ming-Liang 2012 3 5 1629 1633 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Mechanistic understanding of Rh-catalyzed <i>N</i>-sulfonylaldimine insertion into aryl C–H bonds 10.1039/c2sc01081j Li Yang Zhang Xi-Sha Li Hu Wang Wen-Hua Chen Kang Li Bi-Jie Shi Zhang-Jie 2012 3 5 1634 1639 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Synthetic diversification of natural products: semi-synthesis and evaluation of triazole jadomycins 10.1039/c2sc00663d Dupuis Stephanie N. Robertson Andrew W. Veinot Thomas Monro Susan M. A. Douglas Susan E. Syvitski Ray T. Goralski Kerry B. McFarland Sherri A. Jakeman David L. 2012 3 5 1640 1644 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Direct oxidative arylation <i>via</i> rhodium-catalyzed C–C bond cleavage of secondary alcohols with arylsilanes 10.1039/c2sc00923d Chen Kang Li Hu Li Yang Zhang Xi-Sha Lei Zhi-Quan Shi Zhang-Jie 2012 3 5 1645 1649 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry The intramolecular Diels–Alder reaction of tryptamine-derived Zincke aldehydes is a stepwise process 10.1039/c2sc01072k Pham Hung V. Martin David B. C. Vanderwal Christopher D. Houk K. N. 2012 3 5 1650 1655 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry On the appearance of nitrite anion in [PdX(OAc)L₂] and [Pd(X)(C^N)L] syntheses (X = OAc or NO₂): photocrystallographic identification of metastable Pd(η¹-ONO)(C^N)PPh₃ 10.1039/c2sc01050j Bajwa Somia E. Storr Thomas E. Hatcher Lauren E. Williams Thomas J. Baumann Christoph G. Whitwood Adrian C. Allan David R. Teat Simon J. Raithby Paul R. Fairlamb Ian J. S. 2012 3 5 1656 1661 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Towards organic film passivation of germanium wafers using diazonium salts: Mechanism and ambient stability 10.1039/c2sc01034h Lefèvre Xavier Segut Olivier Jégou Pascale Palacin Serge Jousselme Bruno 2012 3 5 1662 1671 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Metal-free, aerobic ketooxygenation of alkenes using hydroxamic acids 10.1039/c2sc01042a Schmidt Valerie A. Alexanian Erik J. 2012 3 5 1672 1674 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Imidazole-derived carbenes and their elusive tetraazafulvalene dimers 10.1039/c2sc20054f Jolly Phillip I. Zhou Shengze Thomson Douglas W. Garnier Jean Parkinson John A. Tuttle Tell Murphy John A. 2012 3 5 1675 1679 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry A mononuclear carboxylate-rich oxoiron(iv) complex: a structural and functional mimic of TauD intermediate ‘J’ 10.1039/c2sc01044e McDonald Aidan R. Guo Yisong Vu Van V. Bominaar Emile L. Münck Eckard Que  Lawrence 2012 3 5 1680 1693 Abstract HTML PDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Ni(0) or Cu(0) catalyzed cleavage of the unactivated C–Cl bond of 2-chloro-1,1,1-trifluoroethane (HCFC-133a) <i>via</i> a single electron transfer (SET) process 10.1039/c2sc01083f Xiao-Jun Tang Qing-Yun Chen 2012 3 5 1694 1697 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Infrared photodissociation spectra of mass selected homoleptic dinuclear iron carbonyl cluster anions in the gas phase 10.1039/c2sc20119d Chi Chaoxian Cui Jieming Li Zhen Hua Xing Xiaopeng Wang Guanjun Zhou Mingfei 2012 3 5 1698 1706 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Lanthanide ions as required cofactors for DNA catalysts 10.1039/c2sc01067d Dokukin Victor Silverman Scott K. 2012 3 5 1707 1714 Abstract HTMLPDF research-article

Chemical Science 2041-6520 Royal Society of Chemistry Back cover 10.1039/c2sc90016e AuthorAnonymous 2012 3 5 1715 1716 Abstract HTML PDF other