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Dalton Transactions

The leading European journal for inorganic and organometallic chemistry



Bioinorganic and biological inorganic chemistry



Browse research in bioinorganic and biological inorganic chemistry from 2006 here.

Pyridine and phosphonate containing ligands for stable lanthanide complexation. An experimental and theoretical study to assess the solution structure
Marta Mato-Iglesias, Edina Balogh, Carlos Platas-Iglesias, Éva Tóth, Andrés de Blas and Teresa Rodríguez Blas, Dalton Trans., 2006, 5404
DOI: 10.1039/b611544f


New water-soluble platinum(II) phenanthroline complexes tested as cisplatin analogues: first-time comparison of cytotoxic activity between analogous four- and five-coordinate species
Sandra A. De Pascali, Danilo Migoni, Paride Papadia, Antonella Muscella, Santo Marsigliante, Antonella Ciccarese and Francesco P. Fanizzi, Dalton Trans., 2006, 5077
DOI: 10.1039/b610945d


Kinetics of -haematin formation from suspensions of haematin in aqueous benzoic acid
Timothy J. Egan and Mmboneni G. Tshivhase, Dalton Trans., 2006, 5024
DOI: 10.1039/b610866k


Copper(II) binding by fragments of -synuclein containing M1-D2- and -H50-residues; a combined potentiometric and spectroscopic study
Teresa Kowalik-Jankowska, Anna Rajewska, Elbieta Jankowska and Zbigniew Grzonka, Dalton Trans., 2006, 5068
DOI: 10.1039/b610619f


A simple, convenient method to synthesize cobalamins: synthesis of homocysteinylcobalamin, N-acetylcysteinylcobalamin, 2-N-acetylamino-2-carbomethoxyethanethiolatocobalamin, sulfitocobalamin and nitrocobalamin
Edward Suarez-Moreira, Luciana Hannibal, Clyde A. Smith, Roberto A. Chavez, Donald W. Jacobsen and Nicola E. Brasch, Dalton Trans., 2006, 5269
DOI: 10.1039/b610158e


Evidence for intramolecular aromatic-ring stacking in the physiological pH range of the monodeprotonated xanthine residue in mixed-ligand complexes containing xanthosinate 5-monophosphate (XMP)
Helmut Sigel, Bert P. Operschall, Salah S. Massoud, Bin Song and Rolf Griesser, Dalton Trans., 2006, 5521
DOI: 10.1039/b610082a


Cucurbituril binding of trans-[{PtCl(NH3)2}2(µ-NH2(CH2)8NH2)]2+ and the effect on the reaction with cysteine
Mark S. Bali, Damian P. Buck, Andrew J. Coe, Anthony I. Day and J. Grant Collins, Dalton Trans., 2006, 5337
DOI: 10.1039/b609881a


fac-[Re(CO)3(dmso-O)3](CF3SO3): a new versatile and efficient Re(I) precursor for the preparation of mono and polynuclear compounds containing fac-[Re(CO)3]+ fragments
Massimo Casanova, Ennio Zangrando, Fabio Munini, Elisabetta Iengo and Enzo Alessio, Dalton Trans., 2006, 5033
DOI: 10.1039/b609853c


Tuning the gas phase redox properties of copper(II) ternary complexes of terpyridines to control the formation of nucleobase radical cations
Adrian K. Y. Lam, Brendan F. Abrahams, Martin J. Grannas, W. David McFadyen and Richard A. J. O'Hair, Dalton Trans., 2006, 5051
DOI: 10.1039/b609688c


Can an ancillary ligand lead to a thermodynamically stable end-on 1 : 1 Cu–O2 adduct supported by a -diketiminate ligand?
David E. Heppner, Benjamin F. Gherman, William B. Tolman and Christopher J. Cramer, Dalton Trans., 2006, 4773
DOI: 10.1039/b608980a


Crystal structure analysis of [Ca(O3SC18H37)2(DMSO)2], a lamellar coordination polymer and its relevance for model studies in biomineralization
Dirk Volkmer, Norbert Mayr and Marc Fricke, Dalton Trans., 2006, 4889
DOI: 10.1039/b608760d


Carbon dioxide and related heterocumulenes at zinc and lithium cations: bioinspired reactions and principles
Stephan Schenk, Johannes Notni, Uwe Köhn, Kurt Wermann and Ernst Anders, Dalton Trans., 2006, 4191
DOI: 10.1039/b608534b


Copper(II) complexes of terminally protected pentapeptides containing three histidyl residues in alternating positions, Ac-His-Xaa-His-Yaa-His-NH2
Csilla Kállay, Katalin Várnagy, Gerasimos Malandrinos, Nick Hadjiliadis, Daniele Sanna and Imre Sóvágó, Dalton Trans., 2006, 4545
DOI: 10.1039/b608190h


EPR spectroscopy as a probe of metal centres in biological systems
Wilfred R. Hagen, Dalton Trans., 2006, 4415
DOI: 10.1039/b608163k


Ferrocene-modified pyrimidine nucleosides: synthesis, structure and electrochemistry
Haifeng Song, Xiaohong Li, Yitao Long, Gabriele Schatte and Heinz-Bernhard Kraatz, Dalton Trans., 2006, 4696
DOI: 10.1039/b608077d


Structure and O2-reactivity of copper(I) complexes supported by pyridylalkylamine ligands
Shinobu Itoh and Yoshimitsu Tachi, Dalton Trans., 2006, 4531
DOI: 10.1039/b607964d


Metal ion selectivity of oligopeptides
Imre Sóvágó and Katalin sz, Dalton Trans., 2006, 3841
DOI: 10.1039/b607515k


Experimental and computational evidence of the intermolecular motifs in the crystal packing of luminescent pentacoordinated gallium(III) complexes
Alessandra Crispini, Iolinda Aiello, Massimo La Deda, Irene De Franco, Mario Amati, Francesco Lelj and Mauro Ghedini, Dalton Trans., 2006, 5124
DOI: 10.1039/b606895b


Triruthenium and triosmium carbonyl clusters containing chiral bidentate NHC-thiolate ligands derived from levamisole
Javier A. Cabeza, Iván da Silva, Ignacio del Río and M. Gabriela Sánchez-Vega, Dalton Trans., 2006, 3966
DOI: 10.1039/b606869c


Bio-inspired, side-on attachment of a ruthenium photosensitizer to an iron hydrogenase active site model
Jesper Ekström, Maria Abrahamsson, Carol Olson, Jonas Bergquist, Filiz B. Kaynak, Lars Eriksson, Licheng Sun, Hans-Christian Becker, Björn Ĺkermark, Leif Hammarström and Sascha Ott, Dalton Trans., 2006, 4599
DOI: 10.1039/b606659c


From structural properties of the EuIII complex with ethylenediaminetetra(methylenephosphonic acid) (H8EDTMP) towards biomedical applications
Anna Mondry and Rafa Janicki, Dalton Trans., 2006, 4702
DOI: 10.1039/b606420e


On the role of the counter-ion in defining water structure and dynamics: order, structure and dynamics in hydrophilic and hydrophobic gadolinium salt complexes
Amber L. Thompson, David Parker, David A. Fulton, Judith A. K. Howard, Shashi U. Pandya, Horst Puschmann, Kanthi Senanayake, Philip A. Stenson, Alessandra Badari, Mauro Botta, Stefano Avedano and Silvio Aime, Dalton Trans., 2006, 5605
DOI: 10.1039/b606206g


Cu2+ and AMP complexation of enlarged tripodal polyamines
M. Teresa Albelda, Enrique García-Espańa, Hermas R. Jiménez, José M. Llinares, Conxa Soriano, Alejandra Sornosa-Ten and Begońa Verdejo, Dalton Trans., 2006, 4474
DOI: 10.1039/b605639c


Kinetic preference for interaction of cisplatin with the G–C-rich wobble basepair region in both tRNAAla and MhAla
Pal Papsai, Jasmin Aldag, Tina Persson and Sofi K. C. Elmroth, Dalton Trans., 2006, 3515
DOI: 10.1039/b603833f


Carbohydrate–metallocene conjugates: selective formation of a zirconadioxacyclopentane-type dimer from the reaction of a bis(enolate)ZrCp2 reagent with a glucofuranoside derivative
Birgit Meyer zu Berstenhorst, Gerhard Erker, Gerald Kehr and Roland Fröhlich, Dalton Trans., 2006, 3200
DOI: 10.1039/b603803d


Multiple metal binding to 6-oxopurine nucleobases as a source of deprotonation. The role of metal ions at N7 and N3
Marta Morell Cerdŕ, David Amantia, Burkhard Costisella, Andrew Houlton and Bernhard Lippert, Dalton Trans., 2006, 3894
DOI: 10.1039/b603650c


Solution chemistry of 1,15-bis(N,N-dimethyl)-5,11-dioxo-8-(N-benzyl)-1,4,8,12,15-pentaazapentadecane with metal ions of biological interest—Insights toward active metal ion containing therapeutics and diagnostic agents
Thembelani E. Nomkoko, Graham E. Jackson, Bandile S. Nakani and Roger Hunter, Dalton Trans., 2006, 4029
DOI: 10.1039/b602977a


Investigation of the coordination structures of the molybdenum(V) sites of sulfite oxidizing enzymes by pulsed EPR spectroscopy
John H. Enemark, Andrei V. Astashkin and Arnold M. Raitsimring, Dalton Trans., 2006, 3501
DOI: 10.1039/b602919a


Cationic, linear Au(I) N-heterocyclic carbene complexes: synthesis, structure and anti-mitochondrial activity
Murray V. Baker, Peter J. Barnard, Susan J. Berners-Price, Simon K. Brayshaw, James L. Hickey, Brian W. Skelton and Allan H. White, Dalton Trans., 2006, 3708
DOI: 10.1039/b602560a


A positively charged trinuclear 3N-chelated monofunctional platinum complex with high DNA affinity and potent cytotoxicity
Yongmei Zhao, Weijiang He, Pengfei Shi, Jianhui Zhu, Lin Qiu, Liping Lin and Zijian Guo, Dalton Trans., 2006, 2617
DOI: 10.1039/b601739h


meso-[{Ru(phen)2}2(µ-HAT)]4+: a high-affinity DNA hairpin probe {HAT = 1,4,5,8,9,12-hexaazatriphenylene; phen = 1,10-phenanthroline}
Jayden A. Smith, Joy L. Morgan, Adam G. Turley, J. Grant Collins and F. Richard Keene, Dalton Trans., 2006, 3179
DOI: 10.1039/b601073c


Self-assembly of luminescent ternary complexes between seven-coordinate lanthanide(III) complexes and chromophore bearing carboxylates and phosphonates
Simon J. A. Pope, Benjamin P. Burton-Pye, Rory Berridge, Tahir Khan, Peter J. Skabara and Stephen Faulkner, Dalton Trans., 2006, 2907
DOI: 10.1039/b600598e


A tris(2,2-bipyridine)ruthenium(II) derivative tethered to a cis-PtCl2(amine)2 moiety: syntheses, spectroscopic properties, and visible-light-induced scission of DNA
Ken Sakai, Hironobu Ozawa, Hajime Yamada, Taro Tsubomura, Mariko Hara, Akon Higuchi and Masa-aki Haga, Dalton Trans., 2006, 3300
DOI: 10.1039/b600165c


Relaxometric and solution NMR structural studies on ditopic lanthanide(III) complexes of a phosphinate analogue of DOTA with a fast rate of water exchange
Jakub Rudovský, Mauro Botta, Petr Hermann, Avtandil Koridze and Silvio Aime, Dalton Trans., 2006, 2323
DOI: 10.1039/b518147j


Phosphinic derivative of DTPA conjugated to a G5 PAMAM dendrimer: an 17O and 1H relaxation study of its Gd(III) complex
Petra Lebduková, Angélique Sour, Lothar Helm, Éva Tóth, Jan Kotek, Ivan Luke and André E. Merbach, Dalton Trans., 2006, 3399
DOI: 10.1039/b517847a


Breaking the N2 triple bond: insights into the nitrogenase mechanism
Brett M. Barney, Hong-In Lee, Patricia C. Dos Santos, Brian M. Hoffman, Dennis R. Dean and Lance C. Seefeldt, Dalton Trans., 2006, 2277
DOI: 10.1039/b517633f


The enzymatic activation of coenzyme B12
Kenneth L. Brown, Dalton Trans., 2006, 1123
DOI: 10.1039/b517599m


Influence of the stereochemistry of sugars on the selectivity of formation of carbohydrate-derived cyclopentadienyl and indenyl ligands
Richard Laď, Sandrine Martin and Renaud Touret, Dalton Trans., 2006, 3478
DOI: 10.1039/b517146f


New Mn12 single-molecule magnets from edge-sharing bioctahedra
Muralee Murugesu, Wolfgang Wernsdorfer, Khalil A. Abboud, Euan K. Brechin and George Christou, Dalton Trans., 2006, 2285
DOI: 10.1039/b517108c


Inert benzothiazole functionalised ruthenium(II) complexes; potential DNA hairpin binding agents
Caitriona B. Spillane, Joy L. Morgan, Nicholas C. Fletcher, J. Grant Collins and F. Richard Keene, Dalton Trans., 2006, 3122
DOI: 10.1039/b516984d


Double-strand DNA cleavage by copper complexes of 2,2-dipyridyl with electropositive pendants
Yan An, Ming-Liang Tong, Liang-Nian Ji and Zong-Wan Mao, Dalton Trans., 2006, 2066
DOI: 10.1039/b516132k


Model studies of the CuB site of cytochrome c oxidase utilizing a Zn(II) complex containing an imidazole–phenol cross-linked ligand
Russell P. Pesavento, Derek A. Pratt, Jerry Jeffers and Wilfred A. van der Donk, Dalton Trans., 2006, 3326
DOI: 10.1039/b516090a


Reinforced molecular recognition as an alternative to rigid receptors
Sijbren Otto, Dalton Trans., 2006, 2861
DOI: 10.1039/b515817f


Engineering emissive europium and terbium complexes for molecular imaging and sensing
Shashi Pandya, Junhua Yu and David Parker, Dalton Trans., 2006, 2757
DOI: 10.1039/b514637b


Active site structures and the redox properties of blue copper proteins: atomic resolution structure of azurin II and electronic structure calculations of azurin, plastocyanin and stellacyanin
Konstantinos Paraskevopoulos, Mahesh Sundararajan, Rajeev Surendran, Michael A. Hough, Robert R. Eady, Ian H. Hillier and S. Samar Hasnain, Dalton Trans., 2006, 3067
DOI: 10.1039/b513942b


Synthesis, structure and dioxygen reactivity of a bis(µ-iodo)dicopper(I) complex supported by the [N-(3,5-di-tert-butyl-2-hydroxybenzyl)-N,N-di-(2-pyridylmethyl)]amine ligand
Svetlana V. Pavlova, Hing Lun To, Edith S. H. Chan, Hung-Wing Li, Thomas C. W. Mak, Hung Kay Lee and Sunney I. Chan, Dalton Trans., 2006, 2232
DOI: 10.1039/b513898a


A new chiral lanthanide NMR probe for the determination of the enantiomeric purity of -hydroxy acids and the absolute configuration of -amino acids in water
Rachel S. Dickins and Alessandra Badari, Dalton Trans., 2006, 3088
DOI: 10.1039/b513814k


New PEG-ylated Mn(III) porphyrins approaching catalytic activity of SOD enzyme
Ines Batini-Haberle, Ivan Spasojevi, Robert D. Stevens, Bruce Bondurant, Ayako Okado-Matsumoto, Irwin Fridovich, eljko Vujakovi and Mark W. Dewhirst, Dalton Trans., 2006, 617
DOI: 10.1039/b513761f


A computational study of oxidation of ruthenium porphyrins via ORuIV and ORuVIO species
Wiktor Zierkiewicz and Timofei Privalov, Dalton Trans., 2006, 1867
DOI: 10.1039/b513482j


Metal complexes in medicinal chemistry: new vistas and challenges in drug design
Katherine H. Thompson and Chris Orvig, Dalton Trans., 2006, 761
DOI: 10.1039/b513476e


Cucurbit[n]uril binding of platinum anticancer complexes
Nial J. Wheate, Damian P. Buck, Anthony I. Day and J. Grant Collins, Dalton Trans., 2006, 451
DOI: 10.1039/b513197a


Probing the mechanism of hypoxia selectivity of copper bis(thiosemicarbazonato) complexes: DFT calculation of redox potentials and absolute acidities in solution
Jason P. Holland, Jennifer C. Green and Jonathan R. Dilworth, Dalton Trans., 2006, 783
DOI: 10.1039/b512656h


Thioester hydrolysis reactivity of zinc hydroxide complexes: investigating reactivity relevant to glyoxalase II enzymes
Lisa M. Berreau, Amrita Saha and Atta M. Arif, Dalton Trans., 2006, 183
DOI: 10.1039/b512515d


New antitumour active platinum compounds containing carboxylate ligands in trans geometry: synthesis, crystal structure and biological activity
Steven van Zutphen, Elena Pantoja, Rosario Soriano, Carlos Soro, Duncan M. Tooke, Anthony L. Spek, Hans den Dulk, Jaap Brouwer and Jan Reedijk, Dalton Trans., 2006, 1020
DOI: 10.1039/b512357g


Synthesis, characterisation, reactivity and in vitro antiamoebic activity of hydrazone based oxovanadium(IV), oxovanadium(V) and µ-bis(oxo)bis{oxovanadium(V)} complexes
Mannar R. Maurya, Shalu Agarwal, Mohammad Abid, Amir Azam, Cerstin Bader, Martin Ebel and Dieter Rehder, Dalton Trans., 2006, 937
DOI: 10.1039/b512326g


Redox behavior of tumor-inhibiting ruthenium(III) complexes and effects of physiological reductants on their binding to GMP
Petra Schluga, Christian G. Hartinger, Alexander Egger, Erwin Reisner, Markus Galanski, Michael A. Jakupec and Bernhard K. Keppler, Dalton Trans., 2006, 1796
DOI: 10.1039/b511792e


A survey of diamagnetic probes for copper2+ binding to the prion protein. 1H NMR solution structure of the palladium2+ bound single octarepeat
Anthony P. Garnett, Christopher E. Jones and John H. Viles, Dalton Trans., 2006, 509
DOI: 10.1039/b511553a


Synthesis, structure and assessment of the cytotoxic properties of 2,5-dimethylazaferrocenyl phosphonates
Konrad Kowalski, Janusz Zakrzewski, Nicholas J. Long, Natsuko Suwaki, David J. Mann and Andrew J. P. White, Dalton Trans., 2006, 571
DOI: 10.1039/b510445a


Metal complex SERMs (selective oestrogen receptor modulators). The influence of different metal units on breast cancer cell antiproliferative effects
Anne Vessičres, Siden Top, Wolfgang Beck, Elizabeth Hillard and Gérard Jaouen, Dalton Trans., 2006, 529
DOI: 10.1039/b509984f


Absorption spectroscopy and binding constants for first-row transition metal complexes of a DOPA-containing peptide
Mary J. Sever and Jonathan J. Wilker, Dalton Trans., 2006, 813
DOI: 10.1039/b509586g


Titanium biomaterials: titania needles in the test of the foraminiferan Bathysiphon argenteus
Kathryn E. Cole and Ann M. Valentine, Dalton Trans., 2006, 430
DOI: 10.1039/b508989a


Solvent effects in the geometric reorganization of an oxo-molybdenum(V) system
Brian W. Kail and Partha Basu, Dalton Trans., 2006, 1419
DOI: 10.1039/b508543h


Bioinorganic and biological inorganic chemistry

Browse the latest research in bioinorganic and biological inorganic chemistry from 2008.

Bioinorganic and biological inorganic chemistry

Browse research in bioinorganic and biological inorganic chemistry from 2007.