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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry



Contents list for Dalton Transactions, issue 21, 2003

Contents List in PDF Format

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Front Cover

front cover image for Dalton Transactions, Issue 21, 2003

Editorial

Organometallic chemistry and catalysis
Robin N. Perutz and David J. Cole-Hamilton,  Dalton Trans., 2003, 21-ix
DOI: 10.1039/b311889d

Perspectives

C–H Activation approaches for the application of molecular recognition to organometallic chemistry and homogeneous catalysis
Robert H. Crabtree,  Dalton Trans., 2003, 3985
DOI: 10.1039/b304125p

Activation of C–F bonds using Cp*2ZrH2: a diversity of mechanisms
William D. Jones,  Dalton Trans., 2003, 3991
DOI: 10.1039/b307232k

Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems
Marina K. Kuimova, Wassim Z. Alsindi, Joanne Dyer, David C. Grills, Omar S. Jina, Pavel Matousek, Anthony W. Parker, Peter Portius, Xue Zhong Sun, Michael Towrie, Claire Wilson, Jixin Yang and Michael W. George,  Dalton Trans., 2003, 3996
DOI: 10.1039/b306303h

Diffusion and NOE NMR spectroscopy. Applications to problems related to coordination chemistry and homogeneous catalysis
Paul S. Pregosin, Eloísa Martínez-Viviente and P. G. Anil Kumar,  Dalton Trans., 2003, 4007
DOI: 10.1039/b305046g

Metal-catalyzed routes to rings, chains and macromolecules based on inorganic elements
Cory A. Jaska, Alexandra Bartole-Scott and Ian Manners,  Dalton Trans., 2003, 4015
DOI: 10.1039/b303764a

Generation and reactivity of sterically hindered iridium carbenes. Competitive - vs.-hydrogen elimination in iridium(III) alkyls
Ernesto Carmona, Margarita Paneque and Manuel L. Poveda,  Dalton Trans., 2003, 4022
DOI: 10.1039/b303710j

The active site and catalytic mechanism of NiFe hydrogenases
Anne Volbeda and Juan C. Fontecilla-Camps,  Dalton Trans., 2003, 4030
DOI: 10.1039/b304316a

Metal-catalyzed synthesis of stereoregular polyketones, polyesters, and polycarbonates
Koji Nakano, Naoyuki Kosaka, Tamejiro Hiyama and Kyoko Nozaki,  Dalton Trans., 2003, 4039
DOI: 10.1039/b304690g

Papers

Synthesis, characterization, and acid–base properties of (N–N)PtIV(CH3)2(OH)2 – x(OCH3)x(x= 0, 1) complexes
Knut Thorshaug, Irene Fjeldahl, Christian Rømming and Mats Tilset,  Dalton Trans., 2003, 4051
DOI: 10.1039/b304475k

C–H and C–C agostic interactions in cycloalkyl tris(pyrazolyl)boratoniobium complexes
Joëlle Jaffart, Marcus L. Cole, Michel Etienne, Meike Reinhold, John E. McGrady and Feliu Maseras,  Dalton Trans., 2003, 4057
DOI: 10.1039/b305296f

cis–trans Isomerisation of CpRe(CO)2(H)(ArF)(ArF= C6FnH5–n; n= 0–5) is the rate determining step in C–H activation of fluoroarenes: a DFT study
Eric Clot, Beatriz Oelckers, A. Hugo Klahn, Odile Eisenstein and Robin N. Perutz,  Dalton Trans., 2003, 4065
DOI: 10.1039/b305064e

C–F Activation and hydrodefluorination of fluorinated alkenes at rhodium
Daniel Noveski, Thomas Braun, Miriam Schulte, Beate Neumann and Hans-Georg Stammler,  Dalton Trans., 2003, 4075
DOI: 10.1039/b306635e

Marked influence of the bridging carbonyl ligands on the photo- and electrochemistry of the clusters [Ru3(CO)8(µ-CO)2(-diimine)](-diimine = 2,2-bipyridine, 4,4-dimethyl-2,2-bipyridine and 2,2-bipyrimidine)
Frank W. Vergeer, Maria J. Calhorda, Pavel Matousek, Michael Towrie and Frantiek Hartl,  Dalton Trans., 2003, 4084
DOI: 10.1039/b303437b

Computational study of the spin-forbidden H2 oxidative addition to 16-electron Fe(0) complexes
Jeremy N. Harvey and Rinaldo Poli,  Dalton Trans., 2003, 4100
DOI: 10.1039/b302916f

Stationary phases composed of sol–gel processed organometallic complexes functionalized with polyethylene glycol
Joachim Büchele, Michael Marzini and Hermann A. Mayer,  Dalton Trans., 2003, 4107
DOI: 10.1039/b304205g

Mesoporous Ta oxide reduced with bis(toluene)Ti: electronic properties and mechanistic considerations of nitrogen cleavage on the low valent surface
Andrei Lezau, Boris Skadtchenko, Michel Trudeau and David Antonelli,  Dalton Trans., 2003, 4115
DOI: 10.1039/b301134h

Nucleophilic addition of phosphines to rhenium allenylidenes. Unprecedented double P–H bond activation to give an 1-P-phospha-1-butadienyl ligand
Maurizio Peruzzini, Pierluigi Barbaro, Valerio Bertolasi, Claudio Bianchini, Isaac de los Rios, Nicoletta Mantovani, Lorenza Marvelli and Roberto Rossi,  Dalton Trans., 2003, 4121
DOI: 10.1039/b303216g

Room-temperature cyclometallation of amines, imines and oxazolines with [MCl2Cp*]2(M = Rh, Ir) and [RuCl2(p-cymene)]2
David L. Davies, Omar Al-Duaij, John Fawcett, Marco Giardiello, Stephen T. Hilton and David R. Russell,  Dalton Trans., 2003, 4132
DOI: 10.1039/b303737a

Redistribution at silicon by ruthenium complexes. Bonding mode of the bridging silanes in Ru2H4(µ-2:2:2:2-SiH4)(PCy3)4 and Ru2H2(µ-2:2-H2Si(OMe)2)3(PCy3)2
Ridha Ben Said, Khansaa Hussein, Jean-Claude Barthelat, Isabelle Atheaux, Sylviane Sabo-Etienne, Mary Grellier, Bruno Donnadieu and Bruno Chaudret,  Dalton Trans., 2003, 4139
DOI: 10.1039/b304122k

Targeting synthetic analogues of the metallo-sulfur active sites of nickel enzymes capable of important catalysis
Matt C. Smith, J. Elaine Barclay, Sian C. Davies, David L. Hughes and David J. Evans,  Dalton Trans., 2003, 4147
DOI: 10.1039/b307175h

Hydrogenase on an electrode: a remarkable heterogeneous catalyst
Sophie E. Lamle, Kylie A. Vincent, Louise M. Halliwell, Simon P. J. Albracht and Fraser A. Armstrong,  Dalton Trans., 2003, 4152
DOI: 10.1039/b306234c

Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: structure/function relationships
Daesung Chong, Irene P. Georgakaki, Rosario Mejia-Rodriguez, Jean Sanabria-Chinchilla, Manuel P. Soriaga and Marcetta Y. Darensbourg,  Dalton Trans., 2003, 4158
DOI: 10.1039/b304283a

Orthopalladated phosphinite complexes as high-activity catalysts for the Suzuki reaction
Robin B. Bedford, Samantha L. Hazelwood (née Welch), Peter N. Horton and Michael B. Hursthouse,  Dalton Trans., 2003, 4164
DOI: 10.1039/b303657j

Copper mediated living radical polymerisation: interactions between monomer and catalyst
Jeetan Lad, Simon Harrisson, Giuseppe Mantovani and David M. Haddleton,  Dalton Trans., 2003, 4175
DOI: 10.1039/b303888b

Rhodium(I) and iridium(I) complexes with bidentate N,N and P,N ligands as catalysts for the hydrothiolation of alkynes
Suzanne Burling, Leslie D. Field, Barbara A. Messerle, Khuong Q. Vuong and Peter Turner,  Dalton Trans., 2003, 4181
DOI: 10.1039/b303774f