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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry



Contents list for Journal of the Chemical Society, Dalton Transactions, issue 5, 2002

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Front Cover

front cover image for Journal of the Chemical Society, Dalton Transactions, Issue 5, 2002

Editorial

Preface
J. Chem. Soc., Dalton Trans., 2002, ix-5
DOI: 10.1039/b201223p

Perspectives

Applications of advanced experimental techniques: high pressure NMR and computer simulations
Lothar Helm and André E. Merbach,  J. Chem. Soc., Dalton Trans., 2002, 633
DOI: 10.1039/b108321j

Tools of the trade in modeling inorganic reactions. From balls and sticks to HOMO's and LUMO's
Tom Ziegler,  J. Chem. Soc., Dalton Trans., 2002, 642
DOI: 10.1039/b106126g

Sterically hindered benzoates: a synthetic strategy for modeling dioxygen activation at diiron active sites in proteins
William B. Tolman, Lawrence Que and Jr.,  J. Chem. Soc., Dalton Trans., 2002, 653
DOI: 10.1039/b108262k

Insights from protein film voltammetry into mechanisms of complex biological electron-transfer reactions
Fraser A. Armstrong,  J. Chem. Soc., Dalton Trans., 2002, 661
DOI: 10.1039/b108359g

Spin state tuning of non-heme iron-catalyzed hydrocarbon oxidations: participation of FeIII–OOH and FeVO intermediates
Kui Chen, Miquel Costas, Lawrence Que and Jr.,  J. Chem. Soc., Dalton Trans., 2002, 672
DOI: 10.1039/b108629d

Papers

In situ spectroscopic studies related to the mechanism of the Friedel–Crafts acetylation of benzene in ionic liquids using AlCl3 and FeCl3
Szilárd Csihony, Hasan Mehdi, Zoltán Homonnay, Attila Vértes, Ödön Farkas and István T. Horváth,  J. Chem. Soc., Dalton Trans., 2002, 680
DOI: 10.1039/b109303g

Low temperature stopped-flow studies in inorganic chemistry
Markus Weitzer, Markus Schatz, Frank Hampel, Frank W. Heinemann and Siegfried Schindler,  J. Chem. Soc., Dalton Trans., 2002, 686
DOI: 10.1039/b107927c

Pulsed-accelerated-flow studies of the temperature dependence of fast reactions
Robert H. Becker, Wenzel P. Bartlett, Edward T. Urbansky and Dale W. Margerum,  J. Chem. Soc., Dalton Trans., 2002, 695
DOI: 10.1039/b107341a

Early photochemical dynamics of organometallic compounds studied by ultrafast time-resolved spectroscopic techniques
Antonín Vlek Jr., Ian R. Farrell, Davina J. Liard, Pavel Matousek, Michael Towrie, Anthony W. Parker, David C. Grills and Michael W. George,  J. Chem. Soc., Dalton Trans., 2002, 701
DOI: 10.1039/b106249m

Carbon–hydrogen bond activation in cyclopentadienyl dimethyl tungsten nitrosyl and carbonyl
Yubo Fan and Michael B. Hall,  J. Chem. Soc., Dalton Trans., 2002, 713
DOI: 10.1039/b108027j

The self-exchange of a nonbonding electron via the outer-sphere pathway: reorganizational energy and electronic coupling matrix element for the V(OH2)62+/3+, Ru(OH2)62+/3+, V(OH2)63+/4+, and Ru(OH2)63+/4+ couples
François P. Rotzinger,  J. Chem. Soc., Dalton Trans., 2002, 719
DOI: 10.1039/b108627h

Quantum mechanical modelling of alkene hydroformylation as catalyzed by xantphos-Rh complexes
Clark R. Landis and Jamal Uddin,  J. Chem. Soc., Dalton Trans., 2002, 729
DOI: 10.1039/b108649a

Activation of H2 by halocarbonyl bis-phosphine and bis-arsine iridium(I) complexes. The use of parahydrogen induced polarisation to detect species present at low concentration and investigate their reactivity
Sarah K. Hasnip, Simon A. Colebrooke, Christopher J. Sleigh, Simon B. Duckett, Diana R. Taylor, Graham K. Barlow and Mike J. Taylor,  J. Chem. Soc., Dalton Trans., 2002, 743
DOI: 10.1039/b107444j

Mechanistic aspects of hydrogen addition during enantioselective rhodium-catalysed reduction of CC double bonds with formic acid/triethylamine or molecular hydrogen
Susanne Lange and Walter Leitner,  J. Chem. Soc., Dalton Trans., 2002, 752
DOI: 10.1039/b108774f

Catalytic ionic hydrogenations of ketones using molybdenum and tungsten complexes
Mark H. Voges and R. Morris Bullock,  J. Chem. Soc., Dalton Trans., 2002, 759
DOI: 10.1039/b107754f

Carbon monoxide activation in homogeneously catalysed reactions: the nature and roles of catalytic promoters
Robin Whyman, Andrew P. Wright, Jonathan A. Iggo and Brian T. Heaton,  J. Chem. Soc., Dalton Trans., 2002, 771
DOI: 10.1039/b107940a

Kinetics and mechanism of the oxidation of sulfur(IV) by iron(III) at metal ion excess
Gábor Lente and István Fábián,  J. Chem. Soc., Dalton Trans., 2002, 778
DOI: 10.1039/b107263c

Kinetics and mechanism of oxidation of thioglycolic acid by hexachloroiridate(IV)
Jiafei Sun and David M. Stanbury,  J. Chem. Soc., Dalton Trans., 2002, 785
DOI: 10.1039/b105951n

Electron-transfer kinetics and equilibria of copper(II/I) complexes with 1,4,7-trithiacyclononane. A square scheme mechanism involving ligand addition
Ashoka Kandegedara, Ksenia Krylova, Timothy J. Nelson, Ronald R. Schroeder, L. A. Ochrymowycz and D. B. Rorabacher,  J. Chem. Soc., Dalton Trans., 2002, 792
DOI: 10.1039/b107449k

Reduction of short chain alkynes by a nitrogenase -70Ala-substituted MoFe protein
Suzanne M. Mayer, Walter G. Niehaus and Dennis R. Dean,  J. Chem. Soc., Dalton Trans., 2002, 802
DOI: 10.1039/b107336b

The reaction of ONOO– with carbonyls: Estimation of the half-lives of ONOOC(O)O– and O2NOOC(O)O–
Sara Goldstein, Johan Lind and Gabor Merényi,  J. Chem. Soc., Dalton Trans., 2002, 808
DOI: 10.1039/b107248j

Studies of copper(II)-binding to bacterioferritin and its effect on iron(II) oxidation
Suzanne Baaghil, Andrew J. Thomson, Geoffrey R. Moore and Nick E. Le Brun,  J. Chem. Soc., Dalton Trans., 2002, 811
DOI: 10.1039/b107288a