Hot paper: The Lithium Extraction/Insertion Mechanism in Li2FeSiO4
07 June 2006

We explain how a fascinating new - above all,
potentially cheap - cathode material
for large-scale Li-ion batteries, typically for
hybrid electric vehicle applications, actually
works in the battery at an atomic level.
Micron-size particles of the material (Li2FeSiO4)
must lose and then regain one of its two Li ions
(along with one electron) as the battery
is cycled. Essentially, we show that this occurs
in a different way during the first cycle
compared to subsequent cycles. The practical
implication could be that the battery
must be precycled in an industrial production process.
- J. O. Thomas
2. What has motivated you to conduct this work?
The need to find cheaper materials to make larger Li-ion
batteries an economically viable proposition. The currently
used materials are prohibitively expensive for upscaling.
3. Where do you see this work developing in the future?
The industrial development of much larger Li-ion batteries for
a whole range of important applications: (hybrid) electric vehicles,
solar-energy storage, emergency power supplies, etc.
4. Are there any particular challenges facing future research in this area?
As stated, sample purity remains a problem, but one which we hope to
solve in the near future. The materials works
well, despite the present impurities.
The lithium extraction/insertion mechanism in Li2FeSiO4
Anton Nytén, Saeed Kamali, Lennart Häggström, Torbjörn Gustafsson and John O. Thomas, J. Mater. Chem., 2006, 16, 2266
DOI: 10.1039/b601184e
