Dangling bonds induce ferromagnetism in graphitic carbon nitride


Researchers in China have achieved ferromagnetism in graphitic carbon nitride, g-C3N4, by introducing hydrogen dangling bonds into its two-dimensional structure, making the material suitable for spintronic devices.

The hydrogen dangling bonds induce intrinsic ferromagnetism in graphitic carbon nitride

Spintronics exploits the intrinsic spin of electrons and their associated magnetic moments and charges to make solid-state devices such as storage media and sensors. Generally, the materials used to make these devices are ferromagnetic, that is, they form permanent magnets. Ultrathin 2D nanosheets can be used to construct such devices because they exhibit spin ordering within their structures.

However, metal-containing ferromagnetic nanosheets generally cannot give large spin relaxation times. Metal-free nanosheets, with only s- and p- electrons, usually show weak spin–orbit coupling and large relaxation times, making them more suitable for use in spintronics. The main issue with current metal-free structures however, is that they lack ordered spin structures, which hampers their ferromagnetic behaviours.

Changzheng Wu, from the Hefei National Laboratory for Physical Sciences at the Microscale, and his coworkers have found that by hydrogenating g-C3N, a graphite-like material with weakly-stacked C—N layers, the material forms hydrogen dangling bonds, inducing spin ordering to the structure.

A dangling bond occurs when an immobilised atom has an unsatisfied valence. In g-C3N4, the carbon and nitrogen atoms are sp2 hybridised and the N atoms have lone pairs of electrons on them, which are immobilised within the structure. The hydrogenation of g-C3N4 is therefore much more energetically accessible than that of graphene, because interactions can occur between the H+ ions and the highly electronegative nitrogen atoms. These interactions are termed ‘hydrogen dangling bonds,’ and have an influence on the spin behaviour of the structure. And essentially, according to Wu, endow ferromagnetism on the material without changing its crystal structure.

A materials scientist, Guihua Yu, at the University of Texas at Austin, US, says that this research ‘presents a new perspective of triggering intrinsic ferromagnetism in 2D metal-free nanomaterials,’ and will widen the scope of 2D ferromagnetic materials. Wu and his colleagues plan to extend this work by introducing dangling bonds and defects into other ultrathin 2D nanosheets to regulate their spin behaviours.

References

This paper is open access. Download it here:

K Xu et al, Chem. Sci., 2014, DOI: 10.1039/c4sc02576h


Related Content

Boron nitride nanotube composites outperform their carbon cousins

14 January 2016 Research

news image

Binding strengths of polymer–boron nitride nanotubes are higher than those reported for carbon nanotubes

What is a bond?

30 January 2014 Premium contentFeature

news image

There’s more to bonding than covalent, ionic and the lines we draw between atoms on paper. Philip Ball takes on the expandi...

Most Commented

Large HIV vaccine trial to launch in South Africa

24 May 2016 News and Analysis

news image

US funding agency will enlist 5400 people for HIV vaccine study in South Africa in November

Crawling chemical system acts as if it’s alive

24 May 2016 Research

news image

Intriguing globule that moves, eats and defecates