Chemists get the ball rolling on titanium oxide fullerenes


The fullerene-type structure consists of seven-coordinate (blue) and five-coordinate (green) titanium, and oxygen (red) © American Chemical Society

Scientists in China have made a titanium oxide cage that closely resembles a fullerene. The shell contains 42 titanium atoms, trumping the previous record of 34 for a titanium–oxo nanocluster.

Since the discovery of C60 buckministerfullerene in 1985, synthetic chemists have attempted to create a wide array of large molecular clusters from the elusive buckyball boron to polyzinc clusters that are challenging our view of aromaticity.

Now, Mei-Yan Gao and colleagues from the Chinese Academy of Sciences have synthesised the first fullerene-like titanium oxide sphere. Formed from the reaction between Ti(OiPr)4 and formic acid in an autoclave, the H6[Ti42(µ3-O)60(OiPr)42(OH)12] structure consists of a Ti12 and Ti30 polyhedron, with a diameter of 1.53nm.

The team was also able to layer the titanium oxide spheres over a thin film, copper-based metal organic framework and take a snapshot of the surface using a transmission electron microscope.

References

M-Y Gao et al, J. Am. Chem. Soc., 2016, 138, 2556 (DOI: 10.1021/jacs.6b00613)


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