Catalysts for re-use
Simple chemistry can make catalysts recoverable and reusable without affecting their performance, claim two polymer chemists at Texas A&M University.
David Bergbreiter and Jun Li attached palladium catalysts to the ends of a widely available polymer, polyisobutylene, and assessed the effectiveness of these 'supported catalysts' for accelerating organic reactions.
They found that the catalysts can be re-used without any degradation in performance and, crucially, can be recovered easily, without precipitation or filtration.
The polymer dissolves in non-polar solvents whereas the substrate and products dissolve in polar solvents. The reaction is therefore carried out in a mixed solvent system; the catalyst can be separated from the substrate and products simply by cooling the reaction mixture until the two solvent phases separate.
Caroline Evans
References
Chem. Commun ., 2004, 42 (DOI: 10.1039/ b312368e)
