Argon - Ar

General Information

Discovery

Argon was discovered in 1894 by Lord Rayleigh and Sir William Ramsey in the UK, although the presence of an inert component in air was suspected by Cavendish in 1785.

Appearance

Argon is a colourless, odourless gas.

Source

The atmosphere contains 0.94% argon. It is obtained commercially from liquid air.

Uses

Argon is used in electric light bulbs and fluorescent tubes at a pressure of about 3 mm. Industrially, it is used as an inert gas shield for arc welding, and as a blanket for the production of titanium and other reactive elements.

Biological Role

Argon has no known biological role.

General Information

Argon is considered to be a very inert gas and does not form true compounds as do others in the same Group. However, it does form clathrates with water and quinol in which the argon atoms are trapped inside a lattice of the other molecules.




  Physical Information    
  Atomic Number   18
  Relative Atomic Mass (12C=12.000)   39.948
  Melting Point/K   84
  Boiling Point/K   87
  Density/kg m-3   1.783 (273K)
  Ground State Electron Configuration   [Ne]3s23p6
  Electron Affinity(M-M-)/kJ mol-1   +35 (calc)


  Key Isotopes          
  nuclide 36Ar 37Ar 38Ar 39Ar 40Ar
  atomic mass 35.968 36.967 37.963 38.964 39.962
  natural abundance 0.337% 0% 0.063% 0% 99.6%
  half-life stable 35 days stable 269 yrs stable


Other Information  
Enthalpy of Fusion/kJ mol-1 1.21
Enthalpy of Vaporisation/kJ mol-1 6.53
     
Oxidation States  
Ar0
  Ionisation Energies/kJ mol-1
  M - M+ 1520.4
  M+ - M2+ 2665.2
  M2+ - M3+ 3928
  M3+ - M4+ 5770
  M4+ - M5+ 7238
  M5+ - M6+ 8811
  M6+ - M7+ 12021
  M7+ - M8+ 13844
  M8+ - M9+ 40759
  M9+ - M10+ 46186