Chromium - Cr

General Information

Discovery

Chromium was discovered in 1780 by N.E. Vanquelin in Paris.

Appearance

Chromium is a blue-white, hard metal, capable of taking a high polish.

Source

Chromium is found principally in the ore chromite, which is found in many places including the former USSR, Turkey, Iran, Finland and the Philippines. Chromium metal is usually produced commercially by reduction of chromium(III) oxide by aluminium, or by electrolysis of chrome alum.

Uses

Chromium is used to harden steel, to manufacture stainless steel and to produce several alloys. It is also used in plating as it prevents corrosion and gives a high-lustre finish. It is also used as a catalyst.

Chromium compounds are valued as pigments for their vivid green, yellow, red and orange colours. The ruby takes its colour from chromium, and chromium added to glass imparts an emerald green colour.

Biological Role

Chromium is an essential trace element, but is carcinogenic in excess. Chromium compounds are toxic.




  Physical Information    
  Atomic Number   24
  Relative Atomic Mass (12C=12.000)   51.996
  Melting Point/K   2130
  Boiling Point/K   2945
  Density/kg m-3   7190 (293K)
  Ground State Electron Configuration   [Ar]3d54s1
  Electron Affinity(M-M-)/kJ mol-1   -94


  Key Isotopes          
  nuclide 50Cr 51Cr 52Cr 53Cr 54Cr
  atomic mass 49.946 50.945 51.941 52.941 53.939
  natural abundance 4.359% 0% 83.79% 9.5% 2.36%
  half-life stable 27.8 days stable stable stable


Other Information  
Enthalpy of Fusion/kJ mol-1 15.3
Enthalpy of Vaporisation/kJ mol-1 341.8
     
Oxidation States  
main Cr+3
others Cr-2, Cr-1, Cr0, Cr+1, Cr+2
  Cr+4, Cr+5, Cr+6
  Ionisation Energies/kJ mol-1
  M - M+ 652.7
  M+ - M2+ 1592
  M2+ - M3+ 2987
  M3+ - M4+ 4740
  M4+ - M5+ 6690
  M5+ - M6+ 8738
  M6+ - M7+ 15550
  M7+ - M8+ 17830
  M8+ - M9+ 20220
  M9+ - M10+ 23580