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Chromium - Cr General Information Discovery Chromium was discovered in 1780 by N.E. Vanquelin in Paris. Appearance Chromium is a blue-white, hard metal, capable of taking a high polish. Source Chromium is found principally in the ore chromite, which is found in many places including the former USSR, Turkey, Iran, Finland and the Philippines. Chromium metal is usually produced commercially by reduction of chromium(III) oxide by aluminium, or by electrolysis of chrome alum. Uses Chromium is used to harden steel, to manufacture stainless steel and to produce several alloys. It is also used in plating as it prevents corrosion and gives a high-lustre finish. It is also used as a catalyst. Chromium compounds are valued as pigments for their vivid green, yellow, red and orange colours. The ruby takes its colour from chromium, and chromium added to glass imparts an emerald green colour. Biological Role Chromium is an essential trace element, but is carcinogenic in excess. Chromium compounds are toxic. |
| Physical Information | |||
| Atomic Number | 24 | ||
| Relative Atomic Mass (12C=12.000) | 51.996 | ||
| Melting Point/K | 2130 | ||
| Boiling Point/K | 2945 | ||
| Density/kg m-3 | 7190 (293K) | ||
| Ground State Electron Configuration | [Ar]3d54s1 | ||
| Electron Affinity(M-M-)/kJ mol-1 | -94 |
| Key Isotopes | ||||||
| nuclide | 50Cr | 51Cr | 52Cr | 53Cr | 54Cr | |
| atomic mass | 49.946 | 50.945 | 51.941 | 52.941 | 53.939 | |
| natural abundance | 4.359% | 0% | 83.79% | 9.5% | 2.36% | |
| half-life | stable | 27.8 days | stable | stable | stable |
| Other Information | ||
| Enthalpy of Fusion/kJ mol-1 | 15.3 | |
| Enthalpy of Vaporisation/kJ mol-1 | 341.8 | |
| Oxidation States | ||
| main | Cr+3 | |
| others | Cr-2, Cr-1, Cr0, Cr+1, Cr+2 | |
| Cr+4, Cr+5, Cr+6 | ||
| Ionisation Energies/kJ mol-1 | ||
| M - M+ | 652.7 | |
| M+ - M2+ | 1592 | |
| M2+ - M3+ | 2987 | |
| M3+ - M4+ | 4740 | |
| M4+ - M5+ | 6690 | |
| M5+ - M6+ | 8738 | |
| M6+ - M7+ | 15550 | |
| M7+ - M8+ | 17830 | |
| M8+ - M9+ | 20220 | |
| M9+ - M10+ | 23580 | |
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