Cobalt - Co

General Information

Discovery

Cobalt was discovered by G. Brandt in 1735 in Stockholm, Sweden.

Appearance

Cobalt is a lustrous, silvery-blue, hard metal.

Source

Cobalt is found in the minerals cobaltite, smaltite and erythrite. Important ore deposits are found in Zaire, Morocco and Canada. There is evidence that the floor of the north central Pacific Ocean may have cobalt-rich deposits.

Uses

Cobalt metal is used in electroplating because of its attractive appearance, hardness and resistance to oxidation. It is alloyed with iron, nickel and other metals, and used in jet turbines and gas turbine generators.

Cobalt salts have been used for centuries to produce brilliant blue colours in porcelain, glass, pottery and enamels.

Radioactive cobalt-60 is used in the treatment of cancer.

Biological Role

Cobalt is an essential trace element, and forms part of the active site of vitamin B12. Cobalt salts in small doses have been found to be effective in correcting mineral deficiencies in certain animals. Cobalt in large doses is carcinogenic. Radioactive artificial cobalt-60 is an important gamma-ray source, and is used extensively as a tracer and radiotherapeutic agent.





  Physical Information    
  Atomic Number   27
  Relative Atomic Mass (12C=12.000)   58.933
  Melting Point/K   1768
  Boiling Point/K   3143
  Density/kg m-3   8900 (293K)
  Ground State Electron Configuration   [Ar]3d74s2
  Electron Affinity(M-M-)/kJ mol-1   -102


  Key Isotopes          
  nuclide 56Co 57Co 58Co 59Co 60Co
  atomic mass 55.940 56.936 57.936 58.933 59.934
  natural abundance 0% 0% 0% 100% 0%
  half-life 77 days 270 days 71.3 days stable 5.26 years


Other Information  
Enthalpy of Fusion/kJ mol-1 15.2
Enthalpy of Vaporisation/kJ mol-1 382.4
     
Oxidation States  
main Co+2
others Co-1, Co0, Co+1,Co+3,
  Co+4, Co+5
  Ionisation Energies/kJ mol-1
  M - M+ 760
  M+ - M2+ 1646
  M2+ - M3+ 3232
  M3+ - M4+ 4950
  M4+ - M5+ 7670
  M5+ - M6+ 9840
  M6+ - M7+ 12400
  M7+ - M8+ 15100
  M8+ - M9+ 17900
  M9+ - M10+ 26600