Dysprosium - Dy

General Information

Discovery

Dysprosium was discovered by P.-E. Lecoq de Boisbaudran in 1886 in Paris, France.

Appearance

Dysprosium is a bright, hard metal with a silvery lustre.

Source

In common with many other lanthanides, dysprosium is found in the minerals monazite and bastnaesite, and in smaller quantities in several other minerals such as xenotime and fergusonite. It can be extracted from these minerals by ion exchange and solvent extraction. It can also be prepared by the reduction of the trifluoride with calcium metal.

Uses

Dysprosium has not yet found many applications. However, it has a high thermal neutron absorption cross-section and a high melting point, and so it may be useful in nuclear control alloys. A dysprosium oxide-nickel cement is used in nuclear reactor control rods, and has the property of absorbing neutrons readily without swelling or contracting under prolonged neutron bombardment.

Biological Role

Dysprosium has no known biological role, and has low toxicity.

General Information

Dysprosium is relatively stable in air at room temperature, and is readily attacked by acids. It is soft enough to be cut with a knife.




  Physical Information    
  Atomic Number   66
  Relative Atomic Mass (12C=12.000)   162.50
  Melting Point/K   1685
  Boiling Point/K   2835
  Density/kg m-3   8550 (293K)
  Ground State Electron Configuration   [Xe]4f106s2
  Electron Affinity(M-M-)/kJ mol-1   not available


  Key Isotopes          
  nuclide 156Dy 158Dy 160Dy 161Dy 162Dy
  atomic mass 155.9 157.9 159.9 160.9 161.9
  natural abundance 0.06% 0.10% 2.34% 18.9% 25.5%
  half-life stable stable stable stable stable
 
  nuclide 163Dy 164Dy      
  atomic mass 162.9 163.9      
  natural abundance 24.9% 28.2%      
  half-life stable stable      


Other Information  
Enthalpy of Fusion/kJ mol-1 17.2
Enthalpy of Vaporisation/kJ mol-1 293
     
Oxidation States  
main Dy+3
others Dy+2, Dy+4
  Ionisation Energies/kJ mol-1
  M - M+ 571.9
  M+ - M2+ 1126
  M2+ - M3+ 2200
  M3+ - M4+ 4001
  M4+ - M5+  
  M5+ - M6+  
  M6+ - M7+  
  M7+ - M8+  
  M8+ - M9+  
  M9+ - M10+