Erbium - Er

General Information

Discovery

Erbium was discovered by C.G. Mosander in 1842 in Stockholm, Sweden. It was first produced in reasonably pure form in 1934 by Klemm and Bonner.

Appearance

Erbium is a silver-grey metal, and is soft and malleable.

Source

Erbium is found principally in the minerals monazite and bastnaesite, from which it can be extracted by ion exchange and solvent extraction.

Uses

Erbium is occasionally used in infra-red absorbing glass. Added to vanadium, it lowers the hardness and improves the workability. Otherwise it is little used.

Biological Role

Erbium has no known biological role, and has low toxicity.

General Information

Erbium slowly tarnishes in air, reacts slowly with water and reacts with acids.




  Physical Information    
  Atomic Number   68
  Relative Atomic Mass (12C=12.000)   167.26
  Melting Point/K   1802
  Boiling Point/K   3136
  Density/kg m-3   9066 (298K)
  Ground State Electron Configuration   [Xe]4f126s2
  Electron Affinity(M-M-)/kJ mol-1   -50


  Key Isotopes          
  nuclide 162Er 164Er 166Er 167Er 168Er
  atomic mass 161.9 163.9 165.9 166.9 167.9
  natural abundance 0.14% 1.56% 33.4% 22.9% 27.1%
  half-life stable stable stable stable stable
 
  nuclide 169Er 170Er 171Er    
  atomic mass   169.9      
  natural abundance 0% 14.9% 0%    
  half-life 9.4 days stable 7.52 h    


Other Information  
Enthalpy of Fusion/kJ mol-1 17.2
Enthalpy of Vaporisation/kJ mol-1 280
     
Oxidation States  
Er+3  
  Ionisation Energies/kJ mol-1
  M - M+ 588.7
  M+ - M2+ 1151
  M2+ - M3+ 2194
  M3+ - M4+ 4115
  M4+ - M5+  
  M5+ - M6+  
  M6+ - M7+  
  M7+ - M8+  
  M8+ - M9+  
  M9+ - M10+