Europium - Eu

General Information

Discovery

Europium was discovered by E.A. Demaraçy in 1901 in Paris, France. The pure metal has only recently been prepared.

Appearance

Europium is a soft, silvery-white metal.

Source

In common with other lanthanides, europium is found principally in the minerals monazite and bastnaesite, from which it can be prepared. However, the usual method of preparation is by heating europium(Ill) oxide with an excess of lanthanum under vacuum.

Uses

Europium can absorb more neutrons per atom than any other element, making it valuable in control rods for nuclear reactors. Europium-doped plastic has been used as a laser material. Otherwise this element is very little used.

Biological Role

Europium has no known biological role, and has low toxicity.

General Information

Europium is the costliest and one of the rarest of the lanthanides. It is as soft as lead and ductile, and is the most reactive of the lanthanide metals, reacting rapidly with water and air.




  Physical Information    
  Atomic Number   63
  Relative Atomic Mass (12C=12.000)   151.97
  Melting Point/K   1095
  Boiling Point/K   1870
  Density/kg m-3   5243 (293K)
  Ground State Electron Configuration   [Xe]4f76s2
  Electron Affinity(M-M-)/kJ mol-1   -50


  Key Isotopes          
  nuclide 151Eu 152Eu 153Eu    
  atomic mass 150.9   152.9    
  natural abundance 47.8% 0% 52.2%    
  half-life stable 12.7 yrs stable    


Other Information  
Enthalpy of Fusion/kJ mol-1 10.5
Enthalpy of Vaporisation/kJ mol-1 176
     
Oxidation States  
main Eu+3
others Eu+2
  Ionisation Energies/kJ mol-1
  M - M+ 546.7
  M+ - M2+ 1085
  M2+ - M3+ 2404
  M3+ - M4+ 4110
  M4+ - M5+  
  M5+ - M6+  
  M6+ - M7+  
  M7+ - M8+  
  M8+ - M9+  
  M9+ - M10+