Holmium - Ho

General Information

Discovery

The spectral absorption bands of holmium were first identified by M. Delafontaine and J.L. Soret in 1878 in Geneva, Switzerland. The element was independently discovered by P.T. Cleve in 1878 in Uppsala, Sweden.

Appearance

Holmium is a silvery metal with a bright lustre.

Source

The principal source of holmium is the mineral monazite, from which it is obtained by ion exchange and solvent extraction. It can also be obtained by reduction of the anhydrous fluoride by calcium metal.

Uses

Holmium can absorb fission-bred neutrons, so is used in nuclear reactors to keep a chain reaction under control. It is little used otherwise.

Biological Role

Holmium has no known biological role, and is non-toxic.

General Information

Holmium is relatively soft and malleable. It is slowly attacked by water and oxygen, and reacts with acid.




  Physical Information    
  Atomic Number   67
  Relative Atomic Mass (12C=12.000)   164.93
  Melting Point/K   1747
  Boiling Point/K   2968
  Density/kg m-3   8795 (298K)
  Ground State Electron Configuration   [Xe]4f116s2
  Electron Affinity(M-M-)/kJ mol-1   -50


  Key Isotopes          
  nuclide 165Ho 166Ho      
  atomic mass 164.9        
  natural abundance 100% 0%      
  half-life stable 26.9 h      


Other Information  
Enthalpy of Fusion/kJ mol-1 17.2
Enthalpy of Vaporisation/kJ mol-1 303
     
Oxidation States  
Ho+3  
  Ionisation Energies/kJ mol-1
  M - M+ 580.7
  M+ - M2+ 1139
  M2+ - M3+ 2204
  M3+ - M4+ 4100
  M4+ - M5+  
  M5+ - M6+  
  M6+ - M7+  
  M7+ - M8+  
  M8+ - M9+  
  M9+ - M10+