Indium - In

General Information

Discovery

Indium was discovered by F. Reich and H. Richter in 1863 in Freiberg, Germany.

Appearance

Indium is a very soft, silvery-white metal with a brilliant lustre.

Source

Indium is often associated with zinc minerals and iron, lead and copper ores. It is commercially produced from the zinc minerals, usually as a by-product.

Uses

Indium has semiconductor uses in transistors, thermistors and photoconductors. It is also used to make low-temperature alloys; for example, an alloy of 24% indium-76% gallium is liquid at room temperature. Indium can also be plated on to metal and evaporated on to glass to give a mirror with better resistance to corrosion than silver. A tiny long-lived indium battery has been devised to power new electronic watches.

Biological Role

Indium has no known biological role but has been shown to cause birth defects. It has low toxicity.

General Information

Indium is stable in air and with water, but reacts with acids.




  Physical Information    
  Atomic Number   49
  Relative Atomic Mass (12C=12.000)   114.82
  Melting Point/K   429
  Boiling Point/K   2353
  Density/kg m-3   7310 (298K)
  Ground State Electron Configuration   [Kr]4d105s25p1
  Electron Affinity(M-M-)/kJ mol-1   -34


  Key Isotopes          
  nuclide 111In 113In 115In
  atomic mass   112.9 114.9    
  natural abundance 0% 4.3% 95.7%    
  half-life 2.81 days stable 6x1014 yrs    


Other Information  
Enthalpy of Fusion/kJ mol-1 3.27
Enthalpy of Vaporisation/kJ mol-1 231.8
     
Oxidation States  
main In+3
others In+1, In+2
  Ionisation Energies/kJ mol-1
  M - M+ 558.3
  M+ - M2+ 1820.6
  M2+ - M3+ 2704
  M3+ - M4+ 5200
  M4+ - M5+ 7400
  M5+ - M6+ 9500
  M6+ - M7+ 11700
  M7+ - M8+ 13900
  M8+ - M9+ 17200
  M9+ - M10+ 19700