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Krypton - Kr General Information Discovery Krypton was discovered by Sir William Ramsay and M.W. Travers in 1898 in London, in the residue remaining after nitrogen and oxygen had boiled away from liquid air. Appearance Krypton is a colourless, odourless gas. Source Krypton is obtained by distillation from liquid air. Uses Krypton is used commercially as a low-pressure filling gas for fluorescent lights. It is also used in certain photographic flash lamps for high-speed photography. Radioactive krypton was used to estimate Soviet nuclear production. The gas is a product of all nuclear reactors, so the Russian share was found by subtracting the amount that comes from Western reactors from the total in the air. Biological Role Krypton has no known biological role. General Information The spectral lines of krypton - brilliant green and orange - are easily produced and very sharp. The orange-red line of 86Kr is used as the fundamental unit of length: 1 metre=1650763.73 wavelengths. Some krypton compounds can be made, including krypton(II) fluoride, and some clathrates. |
| Physical Information | |||
| Atomic Number | 36 | ||
| Relative Atomic Mass (12C=12.000) | 83.8 | ||
| Melting Point/K | 117 | ||
| Boiling Point/K | 121 | ||
| Density/kg m-3 | 3.75 (gas, 273K) | ||
| Ground State Electron Configuration | [Ar]3d104s24p6 | ||
| Electron Affinity(M-M-)/kJ mol-1 | +39 |
| Key Isotopes | ||||||
| nuclide | 78Kr | 80Kr | 82Kr | 83Kr | 84Kr | |
| atomic mass | 77.92 | 79.92 | 81.91 | 82.91 | 83.91 | |
| natural abundance | 0.35% | 2.25% | 11.6% | 11.5% | 57.0% | |
| half-life | stable | stable | stable | stable | stable | |
| nuclide | 85Kr | 86Kr | ||||
| atomic mass | 84.91 | 85.91 | ||||
| natural abundance | 0% | 17.3% | ||||
| half-life | 10.76 yrs | stable | ||||
| Other Information | ||
| Enthalpy of Fusion/kJ mol-1 | 1.64 | |
| Enthalpy of Vaporisation/kJ mol-1 | 9.05 | |
| Oxidation States | ||
| Kr0, Kr+2 | ||
| Ionisation Energies/kJ mol-1 | ||
| M - M+ | 1350.7 | |
| M+ - M2+ | 2350 | |
| M2+ - M3+ | 3565 | |
| M3+ - M4+ | 5070 | |
| M4+ - M5+ | 6240 | |
| M5+ - M6+ | 7570 | |
| M6+ - M7+ | 10710 | |
| M7+ - M8+ | 12200 | |
| M8+ - M9+ | 22229 | |
| M9+ - M10+ | 28900 | |
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