Krypton - Kr

General Information

Discovery

Krypton was discovered by Sir William Ramsay and M.W. Travers in 1898 in London, in the residue remaining after nitrogen and oxygen had boiled away from liquid air.

Appearance

Krypton is a colourless, odourless gas.

Source

Krypton is obtained by distillation from liquid air.

Uses

Krypton is used commercially as a low-pressure filling gas for fluorescent lights. It is also used in certain photographic flash lamps for high-speed photography. Radioactive krypton was used to estimate Soviet nuclear production. The gas is a product of all nuclear reactors, so the Russian share was found by subtracting the amount that comes from Western reactors from the total in the air.

Biological Role

Krypton has no known biological role.

General Information

The spectral lines of krypton - brilliant green and orange - are easily produced and very sharp. The orange-red line of
86Kr is used as the fundamental unit of length: 1 metre=1650763.73 wavelengths. Some krypton compounds can be made, including krypton(II) fluoride, and some clathrates.



  Physical Information    
  Atomic Number   36
  Relative Atomic Mass (12C=12.000)   83.8
  Melting Point/K   117
  Boiling Point/K   121
  Density/kg m-3   3.75 (gas, 273K)
  Ground State Electron Configuration   [Ar]3d104s24p6
  Electron Affinity(M-M-)/kJ mol-1   +39


  Key Isotopes          
  nuclide 78Kr 80Kr 82Kr 83Kr 84Kr
  atomic mass 77.92 79.92 81.91 82.91 83.91
  natural abundance 0.35% 2.25% 11.6% 11.5% 57.0%
  half-life stable stable stable stable stable
 
  nuclide 85Kr 86Kr      
  atomic mass 84.91 85.91      
  natural abundance 0% 17.3%      
  half-life 10.76 yrs stable      


Other Information  
Enthalpy of Fusion/kJ mol-1 1.64
Enthalpy of Vaporisation/kJ mol-1 9.05
     
Oxidation States  
Kr0, Kr+2  
  Ionisation Energies/kJ mol-1
  M - M+ 1350.7
  M+ - M2+ 2350
  M2+ - M3+ 3565
  M3+ - M4+ 5070
  M4+ - M5+ 6240
  M5+ - M6+ 7570
  M6+ - M7+ 10710
  M7+ - M8+ 12200
  M8+ - M9+ 22229
  M9+ - M10+ 28900