Molybdenum - Mo

General Information

Discovery

Molybdenum was discovered by P.J. Hjelm in 1781 in Uppsala, Sweden.

Appearance

The metal is silver-white and fairly soft when pure. It is usually obtained as a grey powder.

Source

The main source of this element is the ore molybdenite. Molybdenum can be obtained from this ore, but most commercial production is as a by-product of copper production.

Uses

Molybdenum is a valuable alloying agent, as it contributes to the hardness and toughness of quenched and tempered steels. It is also used in certain nickel-based alloys which are heat-resistant and corrosion-resistant to chemical solutions. It has found use in electrical and nuclear applications, and as a catalyst in the refining of petroleum.

Biological Role

Although it is toxic in anything other than small quantities, molybdenum is an essential element for animals and plants. If soil lacks this element the land is barren. Leguminous plants use the nitrogen-fixing enzyme nitrogenase, which contains molybdenum.




  Physical Information    
  Atomic Number   42
  Relative Atomic Mass (12C=12.000)   95.94
  Melting Point/K   2890
  Boiling Point/K   4885
  Density/kg m-3   10220 (293K)
  Ground State Electron Configuration   [Kr]4d55s1
  Electron Affinity(M-M-)/kJ mol-1   -114


  Key Isotopes          
  nuclide 92Mo 94Mn 95Mo 96Mo 97Mo
  atomic mass 91.91 93.90 94.91 95.90 96.91
  natural abundance 14.84% 9.25% 15.92% 16.68% 9.55%
  half-life stable stable stable stable stable
  nuclide 98Mo 99Mo 100Mo
  atomic mass 97.91   99.91    
  natural abundance 24.13% 0% 9.63%    
  half-life stable 66.69 h stable    


Other Information  
Enthalpy of Fusion/kJ mol-1 27.6
Enthalpy of Vaporisation/kJ mol-1 589.9
     
Oxidation States  
main Mo+6
others Mo-2, Mo0, Mo+1, Mo+2,
  Mo+3, Mo+4, Mo+5
  Ionisation Energies/kJ mol-1
  M - M+ 685
  M+ - M2+ 1558
  M2+ - M3+ 2621
  M3+ - M4+ 4480
  M4+ - M5+ 5900
  M5+ - M6+ 6560
  M6+ - M7+ 12230
  M7+ - M8+ 14800
  M8+ - M9+ 16800
  M9+ - M10+ 19700