Platinum - Pt

General Information

Discovery

Platinum was discovered by South Americans and taken to Europe about 1750. The metal was used by pre-Columbian Indians.

Appearance

Platinum is a beautiful silvery-white metal, and is malleable and ductile.

Source

Platinum is found uncombined in alluvial deposits, and prepared commercially as a by-product of nickel refining from copper-nickel ores.

Uses

Platinum is used extensively for jewellery, wire and many valuable instruments including thermocouple elements. It is also used for electrical contacts, corrosion-resistance apparatus and in dentistry. In a finely divided state platinum absorbs large volumes of hydrogen and so is used as a catalyst in the petroleum cracking industry.

Biological Role

Platinum has no known biological role, and is non-toxic.

General Information

Platinum is not affected by air or water at any temperature. It is insoluble in hydrochloric and nitric acids, but dissolves when they are mixed to form aqua regia.

The price of platinum fluctuates, but it can cost eight times as much as gold.




  Physical Information    
  Atomic Number   78
  Relative Atomic Mass (12C=12.000)   195.08
  Melting Point/K   2045
  Boiling Point/K   4100
  Density/kg m-3   21450 (293K)
  Ground State Electron Configuration   [Xe]4f145d96s1
  Electron Affinity(M-M-)/kJ mol-1   -247


  Key Isotopes          
  nuclide 190Pt 192Pt 194Pt 195Pt 196Pt
  atomic mass 189.96 191.96 193.96 194.96 195.96
  natural abundance 0.01% 0.79% 32.9% 33.8% 25.3%
  half-life 6.9x1011 yrs 1015 yrs stable stable stable
 
  nuclide 197Pt 198Pt      
  atomic mass   197.97      
  natural abundance 0% 7.2%      
  half-life 18 h stable      


Other Information  
Enthalpy of Fusion/kJ mol-1 19.7
Enthalpy of Vaporisation/kJ mol-1 469
     
Oxidation States  
main Pt+4
others Pt0, Pt+2, Pt+5, Pt+6
  Ionisation Energies/kJ mol-1
  M - M+ 870
  M+ - M2+ 1791
  M2+ - M3+ 2800
  M3+ - M4+ 3900
  M4+ - M5+ 5300
  M5+ - M6+ 7200
  M6+ - M7+ 8900
  M7+ - M8+ 10500
  M8+ - M9+ 12300
  M9+ - M10+ 14100