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Platinum - Pt General Information Discovery Platinum was discovered by South Americans and taken to Europe about 1750. The metal was used by pre-Columbian Indians. Appearance Platinum is a beautiful silvery-white metal, and is malleable and ductile. Source Platinum is found uncombined in alluvial deposits, and prepared commercially as a by-product of nickel refining from copper-nickel ores. Uses Platinum is used extensively for jewellery, wire and many valuable instruments including thermocouple elements. It is also used for electrical contacts, corrosion-resistance apparatus and in dentistry. In a finely divided state platinum absorbs large volumes of hydrogen and so is used as a catalyst in the petroleum cracking industry. Biological Role Platinum has no known biological role, and is non-toxic. General Information Platinum is not affected by air or water at any temperature. It is insoluble in hydrochloric and nitric acids, but dissolves when they are mixed to form aqua regia. The price of platinum fluctuates, but it can cost eight times as much as gold. |
| Physical Information | |||
| Atomic Number | 78 | ||
| Relative Atomic Mass (12C=12.000) | 195.08 | ||
| Melting Point/K | 2045 | ||
| Boiling Point/K | 4100 | ||
| Density/kg m-3 | 21450 (293K) | ||
| Ground State Electron Configuration | [Xe]4f145d96s1 | ||
| Electron Affinity(M-M-)/kJ mol-1 | -247 |
| Key Isotopes | ||||||
| nuclide | 190Pt | 192Pt | 194Pt | 195Pt | 196Pt | |
| atomic mass | 189.96 | 191.96 | 193.96 | 194.96 | 195.96 | |
| natural abundance | 0.01% | 0.79% | 32.9% | 33.8% | 25.3% | |
| half-life | 6.9x1011 yrs | 1015 yrs | stable | stable | stable | |
| nuclide | 197Pt | 198Pt | ||||
| atomic mass | 197.97 | |||||
| natural abundance | 0% | 7.2% | ||||
| half-life | 18 h | stable | ||||
| Other Information | ||
| Enthalpy of Fusion/kJ mol-1 | 19.7 | |
| Enthalpy of Vaporisation/kJ mol-1 | 469 | |
| Oxidation States | ||
| main | Pt+4 | |
| others | Pt0, Pt+2, Pt+5, Pt+6 | |
| Ionisation Energies/kJ mol-1 | ||
| M - M+ | 870 | |
| M+ - M2+ | 1791 | |
| M2+ - M3+ | 2800 | |
| M3+ - M4+ | 3900 | |
| M4+ - M5+ | 5300 | |
| M5+ - M6+ | 7200 | |
| M6+ - M7+ | 8900 | |
| M7+ - M8+ | 10500 | |
| M8+ - M9+ | 12300 | |
| M9+ - M10+ | 14100 | |
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