Tantalum - Ta

General Information

Discovery

Tantalum was discovered by A.G. Ekeberg in 1802 in Uppsala, Sweden, but many chemists thought that tantalum and niobium were identical elements until Rose (in 1844) and Marignac (in 1866) showed that niobic and tantalic acids were different.

Appearance

Tantalum is a shiny, grey metal which is soft when pure.

Source

Tantalum occurs principally in the mineral columbite-tantalite, found in many places including Australia, Canada and Africa. Separation of tantalum from niobium requires several complicated steps. It is obtained commercially as a by-product of tin extraction.

Uses

Tantalum causes no immune response in mammals, so has found wide use in the making of surgical appliances. It can replace bone, for example in skull plates; as foil or wire it connects torn nerves; as woven gauze it binds abdominal muscle. Tantalum has also been used to make a variety of alloys.

Biological Role

Tantalum has no known biological role, and is non-toxic.

General Information

Tantalum is very corrosion resistant due to the formation of an oxide film, but is attacked by hydrogen fluoride and fused alkalis. It has a melting point exceeded only by tungsten and rhenium.




  Physical Information    
  Atomic Number   73
  Relative Atomic Mass (12C=12.000)   180.95
  Melting Point/K   3269
  Boiling Point/K   5698
  Density/kg m-3   16654 (293K)
  Ground State Electron Configuration   [Xe]4f145d36s2
  Electron Affinity(M-M-)/kJ mol-1   -14


  Key Isotopes          
  nuclide 180Ta 181Ta 182Ta    
  atomic mass 179.9 180.9      
  natural abundance 0.012% 99.99% 0%    
  half-life 1x1012 yrs stable 115.1 days    


Other Information  
Enthalpy of Fusion/kJ mol-1 31.4
Enthalpy of Vaporisation/kJ mol-1 758.2
     
Oxidation States  
main Ta+5
others Ta-3, Ta-1, Ta+1, Ta+2,
  Ta+3, Ta+6
  Ionisation Energies/kJ mol-1
  M - M+ 761
  M+ - M2+ 1500
  M2+ - M3+ 2100
  M3+ - M4+ 3200
  M4+ - M5+ 4300
  M5+ - M6+  
  M6+ - M7+  
  M7+ - M8+  
  M8+ - M9+  
  M9+ - M10+