Terbium - Tb

General Information

Discovery

Terbium was discovered by C.G. Mosander in 1843 in Stockholm, Sweden.

Appearance

Terbium is a silver-grey metal, malleable, ductile, and soft enough to be cut with a knife.

Source

Terbium can be recovered from the mineral monazite by ion exchange and solvent extraction, and from euxenite, a complex oxide containing 1% or more of terbium. It is usually produced commercially by reducing the anhydrous fluoride or chloride with calcium metal.

Uses

Terbium is used to dope calcium fluoride, calcium tungstate and strontium molybdate, all used in solid-state devices. Terbium salts are used in laser devices, but otherwise this element is not widely used.

Biological Role

Terbium has no known biological role, and has low toxicity.

General Information

Terbium is slowly oxidised by air, and reacts with cold water.




  Physical Information    
  Atomic Number   65
  Relative Atomic Mass (12C=12.000)   158.92
  Melting Point/K   1629
  Boiling Point/K   3396
  Density/kg m-3   8229 (293K)
  Ground State Electron Configuration   [Xe]4f96s2
  Electron Affinity(M-M-)/kJ mol-1   -50


  Key Isotopes          
  nuclide 159Tb 160Tb      
  atomic mass 158.9        
  natural abundance 100% 0%      
  half-life stable 72.1 days      


Other Information  
Enthalpy of Fusion/kJ mol-1 16.3
Enthalpy of Vaporisation/kJ mol-1 391
     
Oxidation States  
Tb+3, Tb+4  
  Ionisation Energies/kJ mol-1
  M - M+ 564.6
  M+ - M2+ 1112
  M2+ - M3+ 2114
M3+ - M4+ 3839
M4+ - M5+  
M5+ - M6+  
M6+ - M7+  
M7+ - M8+  
M8+ - M9+  
M9+ - M10+