Xenon - Xe

General Information

Discovery

Xenon was discovered by Sir William Ramsay and M.W. Travers in 1898 in London.

Appearance

Xenon is a colourless, odourless gas.

Source

Xenon is present in the atmosphere at a concentration of 0.086 parts per million by volume. It can be found in the gases which evolve from certain mineral springs. Commercially it is obtained by extraction from liquid air.

Uses

Xenon is little used outside research. However, it is used in certain specialised light sources which require an instant, intense light such as the high-speed electronic flash bulbs used by photographers. The high volatility of this element's electron structure produces this type of light. Xenon in a vacuum tube produces a beautiful blue glow when excited by an electrical discharge, and finds application in electron tubes, stroboscopic lights and bactericidal lamps.

Biological Role

Xenon has no known biological role. Xenon is not toxic, but its compounds are highly toxic because of their strong oxidising characteristics.

General Information

Xenon is inert towards most other chemicals but reacts with fluorine gas to form xenon fluorides. Xenon oxides, acids and salts are also known.

The first compound of xenon, the first-ever of one of the 'inert gases', was made by Neil Bartlett in 1962 at the University of British Columbia. The importance of this discovery was that it made everyone think again about bonding theory.



  Physical Information    
  Atomic Number   54
  Relative Atomic Mass (12C=12.000)   131.29
  Melting Point/K   161
  Boiling Point/K   166
  Density/kg m-3   5.9 (gas, 273K)
  Ground State Electron Configuration   [Kr]4d105s25p6
  Electron Affinity(M-M-)/kJ mol-1   +41


  Key Isotopes          
  nuclide 127Xe 129Xe 130Xe 131Xe 132Xe
  atomic mass   128.9 129.9 130.9 131.9
  natural abundance 0% 26.4% 4.1% 21.2% 26.9%
  half-life 36.4 days stable stable stable stable
 
  nuclide 133Xe 134Xe 136Xe    
  atomic mass 133.9 135.9    
  natural abundance 0% 10.4% 8.9%    
  half-life 5.27 days stable stable    


Other Information  
Enthalpy of Fusion/kJ mol-1 3.1
Enthalpy of Vaporisation/kJ mol-1 12.65
     
Oxidation States  
main Xe0, Xe+2, Xe+4
others Xe+6, Xe+8
   
Covalent Bonds /kJ mol-1  
Xe - O 84  
  Ionisation Energies/kJ mol-1
  M - M+ 1170.4
  M+ - M2+ 2046
  M2+ - M3+ 3097
  M3+ - M4+ 4300
  M4+ - M5+ 5500
  M5+ - M6+ 6600
  M6+ - M7+ 9300
  M7+ - M8+ 10600
  M8+ - M9+ 19800
  M9+ - M10+ 23000