Issue 5, 1997

The theoretical basis of the isoinversion principle

Abstract

The theoretical basis of the isoinversion principle is discussed in terms of the temperature dependence of absolute rate constants. This description gives an insight into the origin and physical meaning of the terms ‘inversion temperature’ and ‘transition region’. The consequences of quantitative interpretation of non-linear Eyring plots are discussed.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1997, 939-944

The theoretical basis of the isoinversion principle

A. Gypser and P. Norrby, J. Chem. Soc., Perkin Trans. 2, 1997, 939 DOI: 10.1039/A606888J

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