A new iron(III)–carbonato monomeric complex of ortho-phenylenebis(oxamato) (opba) 1 is synthesized, and spectroscopically and structurally characterized; it is a moderately efficient non-heme catalyst for the aerobic epoxidation of alkenes with co-oxidation of pivalaldehyde.
R. Ruiz, M. Triannidis, A. Aukauloo, Y. Journaux, I. Fernández, J. R. Pedro, B. Cervera, I. Castro and M. Carmen Muñoz, Chem. Commun., 1997, 2283 DOI: 10.1039/A705787C
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