Issue 17, 1998
From the journal:

Chemical Communications

Reductive cleavage and related reactions leading to molybdenum–element multiple bonds: new pathways offered by three-coordinate molybdenum(III)

Christopher C. Cummins  

Abstract

Three-coordinate molybdenum(III) complexes comprise a new class of reactive-yet-isolable substances. Related to a well known class of metal–metal triple bonded dimers, the monomeric molybdenum(III) complexes supported by sterically-demanding N-tert-alkylanilide ligands offer previously unavailable synthetic routes to molybdenum–element multiple bonds. Terminal nitride, phosphide and carbide functionalities have been prepared from reactions with dinitrogen, white phosphorus and carbon monoxide, respectively.

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Article information

DOI
https://doi.org/10.1039/A802402B
Article type
Paper

Chem. Commun., 1998, 1777-1786

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Reductive cleavage and related reactions leading to molybdenum–element multiple bonds: new pathways offered by three-coordinate molybdenum(III)

C. C. Cummins, Chem. Commun., 1998, 1777 DOI: 10.1039/A802402B

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