C      3  -Symmetrical lanthanide podates organized by intramolecular trifurcated hydrogen bonds

Fabien Renaud; Claude Piguet; Gérald Bernardinelli; Gérard Hopfgartner; Jean-Claude G. Bünzli

doi:10.1039/A809742I

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C₃-Symmetrical lanthanide podates organized by intramolecular trifurcated hydrogen bonds

Fabien Renaud, Claude Piguet, Gérald Bernardinelli, Gérard Hopfgartner and Jean-Claude G. Bünzli

Abstract

The protonated tripodal podand [L⁶ + H]⁺ forms stable and organized monometallic podates [Ln(L⁶ + H)]⁴⁺ where Ln^III is facially nine-coordinated by three wrapped unsymmetrical tridentate binding units. An unusual trifurcated hydrogen bond assists the organisation of the covalent tripod.

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DOI: https://doi.org/10.1039/A809742I
Article type: Paper

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Chem. Commun., 1999, 457-458

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C ₃ -Symmetrical lanthanide podates organized by intramolecular trifurcated hydrogen bonds

F. Renaud, C. Piguet, G. Bernardinelli, G. Hopfgartner and J. G. Bünzli, Chem. Commun., 1999, 457 DOI: 10.1039/A809742I

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