Issue 11, 1999

A novel two-dimensional honeycomb-like bimetallic iron(III)–nickel(II) cyanide-bridged magnetic material [Ni(cyclam)]3[Fe(CN)6]2·nH2O(cyclam = 1,4,8,11-tetraazacyclodecane)

Abstract

The 2D honeycomb-like layered iron(III)–nickel(II) cyanide-bridged complex [Ni(cyclam)]3[Fe(CN)6]2·nH2O exhibits ferromagnetic intralayer and antiferromagnetic interlayer interactions; above 3 K the magnetic properties are typical of a metamagnet with Hc = 5000 G, whereas below 3 K a canted structure is formed, leading to a long range ferromagnetic ordering.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 987-988

A novel two-dimensional honeycomb-like bimetallic iron(III)–nickel(II) cyanide-bridged magnetic material [Ni(cyclam)]3[Fe(CN)6]2·nH2O(cyclam = 1,4,8,11-tetraazacyclodecane)

E. Colacio, J. M. Domínguez-Vera, M. Ghazi, J. M. Moreno, R. Kivekäs, F. Lloret and H. Stoeckli-Evans, Chem. Commun., 1999, 987 DOI: 10.1039/A902041A

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