Issue 1, 2001
From the journal:

Chemical Communications

Kinetics of formation of the novel peroxide FC(O)OO(O2)SF

María E. Tucceri,a   María P. Badenes,a   Adela E. Crocea  and  Carlos J. Cobos*a  

* Corresponding authors

a Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Departamento de Química, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CONICET, CICBA, Casilla de Correo 16, Sucursal 4, (1900) La Plata, Argentina.
E-mail: cobos@inifta.unlp.edu.ar

Abstract

The high-pressure rate coefficient for the formation of the new peroxide FC(O)OO(O2)SF from recombination of FC(O)O and FS(O2)O radicals has been determined by laser flash photolysis at 296 K; density functional theory calculations indicate peroxide stabilization and allow estimation of an O–O bond dissociation energy of 20.6 ± 3 kcal mol−1.

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Article information

DOI
https://doi.org/10.1039/B006272N
Article type
Communication
Submitted
02 Aug 2000
Accepted
14 Nov 2000
First published
14 Dec 2000

Chem. Commun., 2001, 71-72

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Kinetics of formation of the novel peroxide FC(O)OO(O2)SF

M. E. Tucceri, M. P. Badenes, A. E. Croce and C. J. Cobos, Chem. Commun., 2001, 71 DOI: 10.1039/B006272N

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