Issue 6, 2003
From the journal:

Chemical Communications

Reversible C–C bond formation: solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation†

Lee-Jon Ball,a   Anthony P. Dickie,a   Francis S. Mair,*a   David A. Middletonb  and  Robin G. Pritcharda  

* Corresponding authors

a Department of Chemistry, UMIST, PO Box 88, Manchester, UK
E-mail: frank.mair@umist.ac.uk

b Department of BioMolecular Sciences, UMIST, PO Box 88, Manchester, UK

Abstract

Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C–C bond which ruptures upon dissolution in non-co-ordinating solvents.

Graphical abstract: Reversible C–C bond formation: solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation

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Article information

DOI
https://doi.org/10.1039/B211745B
Article type
Communication
Submitted
27 Nov 2002
Accepted
06 Feb 2003
First published
19 Feb 2003

Chem. Commun., 2003, 744-745

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Reversible C–C bond formation: solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation

L. Ball, A. P. Dickie, F. S. Mair, D. A. Middleton and R. G. Pritchard, Chem. Commun., 2003, 744 DOI: 10.1039/B211745B

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