Issue 13, 2003
From the journal:

Chemical Communications

Snapshots of an oxidatively induced α-hydrogen abstraction reaction to prepare a terminal and four-coordinate titanium imide†

Falguni Basuli,a   Brad C. Bailey,a   John C. Huffmana  and  Daniel J. Mindiola*a  

* Corresponding authors

a Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, Indiana 47405, USA
E-mail: mindiola@indiana.edu
Fax: 001 812 855 8300
Tel: 001 812 855 2399

Abstract

One electron oxidation of the bis-anilido titanium(III) complex (Nacnac)Ti(NHAr)2 (Nacnac− = ArNC(CH3)CHC(CH3)NAr, Ar = 2,6-(CHMe2)2C6H3) with AgOTf affords the cation [(Nacnac)Ti(NHAr)2][OTf] which is isolated and shown to gradually transform, by α-hydrogen abstraction, to the terminal and four-coordinate titanium imide (Nacnac)Ti[double bond, length as m-dash]NAr(OTf).

Graphical abstract: Snapshots of an oxidatively induced α-hydrogen abstraction reaction to prepare a terminal and four-coordinate titanium imide

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Article information

DOI
https://doi.org/10.1039/B304633H
Article type
Communication
Submitted
26 Apr 2003
Accepted
13 May 2003
First published
02 Jun 2003

Chem. Commun., 2003, 1554-1555

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Snapshots of an oxidatively induced α-hydrogen abstraction reaction to prepare a terminal and four-coordinate titanium imide

F. Basuli, B. C. Bailey, J. C. Huffman and D. J. Mindiola, Chem. Commun., 2003, 1554 DOI: 10.1039/B304633H

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