Issue 6, 1997

Absolute kinetics of mesitylmethylchlorocarbene reactions

Abstract

Absolute rate constants were determined for reactions of mesitylmethylchlorocarbene, which affords intramolecular products derived from 1,2-H migration, 1,2-mesityl migration, and C–H insertion; at -35 or -70 °C, however, the intrusion of intermolecular channels affords azine and carbene dimer, complicating interpretations of the kin-etics.

Article information

Article type
Paper

Chem. Commun., 1997, 617-618

Absolute kinetics of mesitylmethylchlorocarbene reactions

R. A. Moss and D. C. Merrer, Chem. Commun., 1997, 617 DOI: 10.1039/A607552E

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