Issue 14, 2003
From the journal:

Chemical Communications

A novel silica catalysed stereoselective cyclic carbamate and carbonate rearrangement

Lorenzo Caggiano,a   John Davies,a   David J. Fox,a   David C. Moodya  and  Stuart Warren*a  

* Corresponding authors

a University Chemistry Laboratory, Lensfield Road, Cambridge, UK
E-mail: sw134@cam.ac.uk

Abstract

Phenylsulfanyl-containing five- and six-membered lactones, cyclic carbamates and carbonates stereospecifically interconvert in the presence of silica gel via thiiranium ions.

Graphical abstract: A novel silica catalysed stereoselective cyclic carbamate and carbonate rearrangement

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Article information

DOI
https://doi.org/10.1039/B303791F
Article type
Communication
Submitted
04 Apr 2003
Accepted
30 May 2003
First published
12 Jun 2003

Chem. Commun., 2003, 1650-1651

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A novel silica catalysed stereoselective cyclic carbamate and carbonate rearrangement

L. Caggiano, J. Davies, D. J. Fox, D. C. Moody and S. Warren, Chem. Commun., 2003, 1650 DOI: 10.1039/B303791F

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