Issue 18, 2003
From the journal:

Chemical Communications

Heterobimetallic lithium alkyltriimido aluminate cages containing the [R′Al(NR)3]4− tetraanion (R′ = Bun, Et; R = 2-OMeC6H4)†

May C. Copsey,a   John C. Jeffery,a   Christopher A. Russell,*a   John M. Slatterya  and  Jennifer A. Straughana  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK
E-mail: chris.russell@bris.ac.uk
Fax: +44 (0)117 9290509
Tel: +44 (0)117 9287599

Abstract

Attempted metallation of a triamidoaluminane gives a complex containing the [R′Al(NR) 3 ] 4− anion whose formal tetranegative charge is the highest charge observed crystallographically for a simple mononuclear imido main group anion system.
Graphical abstract: Heterobimetallic lithium alkyltriimido aluminate cages containing the [R′Al(NR)3]4− tetraanion (R′ = Bun, Et; R = 2-OMeC6H4)

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B307589C
Article type
Communication
Submitted
03 Jul 2003
Accepted
01 Aug 2003
First published
12 Aug 2003

Chem. Commun., 2003, 2356-2357

Permissions

Request permissions

Heterobimetallic lithium alkyltriimido aluminate cages containing the [R′Al(NR)3]4− tetraanion (R′ = Bun, Et; R = 2-OMeC6H4)

M. C. Copsey, J. C. Jeffery, C. A. Russell, J. M. Slattery and J. A. Straughan, Chem. Commun., 2003, 2356 DOI: 10.1039/B307589C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements