Issue 21, 2004
From the journal:

Chemical Communications

Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(ii) complexes with bulky ortho-metalated aryl phosphines

Francisco Estevan,a   Pascual Lahuerta,*a   Julio Lloret,a   Mercedes Sanaú,a   M. Angeles Ubeda*a  and  Jaume Vilaa  

* Corresponding authors

a Departamento de Química Inorgánica, Facultad de Química, Universitat de Valencia, Dr. Moliner 50, Burjassot, Valencia, Spain
E-mail: pascual.lahuerta@uv.es
Fax: (+34) 963544322

Abstract

Enantiomerically pure dirhodium(II) complexes with ortho-metalated p-substituted aryl phosphines have been shown to be enantio- and diastereoselective in the cyclopropanation of styrene by ethyl diazoacetate. Enantioselectivities up to 91% and diastereoselectivities up to 90% are observed for ethyl cis-2-phenylcyclopropanecarboxylate

Graphical abstract: Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(ii) complexes with bulky ortho-metalated aryl phosphines

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B408856E
Article type
Communication
Submitted
11 Jun 2004
Accepted
06 Aug 2004
First published
23 Sep 2004

Chem. Commun., 2004, 2408-2409

Permissions

Request permissions

Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines

F. Estevan, P. Lahuerta, J. Lloret, M. Sanaú, M. A. Ubeda and J. Vila, Chem. Commun., 2004, 2408 DOI: 10.1039/B408856E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements