Issue 9, 2005
From the journal:

Chemical Communications

Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions†

Prokopis C. Andrikopoulos,a   David R. Armstrong,a   Eva Hevia,*a   Alan R. Kennedy,a   Robert E. Mulvey*a  and  Charles T. O'Haraa  

* Corresponding authors

a Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK
E-mail: eva.hevia@strath.ac.uk, r.e.mulvey@strath.ac.uk

Abstract

Toluene is metallated by DABCO-activated disodium tetrabutylmagnesiate, but not by DABCO-activated monosodium tributylmagnesiate; this distinction is rationalised by DFT calculations on model systems, and the crystal structure of the main non-metallated product, which shows interstitial MgBu42− dianions within a polycationic network, is reported.

Graphical abstract: Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

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Article information

DOI
https://doi.org/10.1039/B416636A
Article type
Communication
Submitted
02 Nov 2004
First published
18 Jan 2005

Chem. Commun., 2005, 1131-1133

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Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

P. C. Andrikopoulos, D. R. Armstrong, E. Hevia, A. R. Kennedy, R. E. Mulvey and C. T. O'Hara, Chem. Commun., 2005, 1131 DOI: 10.1039/B416636A

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