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Chem. Commun., 2005, 3909 - 3911, DOI: 10.1039/b502568k

Kinetic isotope effects on thio-substituted biological phosphoryl transfer reactions from density-functional theory

Yun Liu, Xabier Lopez and Darrin M. York

Primary and secondary kinetic and equilibrium isotope effects are calculated with density-functional methods for the dianionic methanolysis of the native (unsubstituted) and thio-substituted ethylene phosphates.

Graphical abstract image for this article (ID: b502568k)