Communication

Chem. Commun., 2007, 3297 - 3299, DOI: 10.1039/b704941b

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Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N₂ complexes

Doris Pun, Emil Lobkovsky and Paul J. Chirik

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Catalytic dehydrogenation of R₂NHBH₃ (R = Me, H) promoted by a family of bis(cyclopentadienyl)titanium and bis(indenyl)zirconium compounds is reported; structure–reactivity relationships as a function of cyclopentadienyl and indenyl substituents have been examined.

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