Issue 45, 2007
From the journal:

Chemical Communications

Enhancing the reactivity of 1,2,3-triazoles in “click” macrocycles by face-to-face dibenzylammonium ion binding†

Yi Liu,*a   Xiyun Zhang,b   Liana M. Klivanskya  and  Gayane Koshkakaryanac  

* Corresponding authors

a The Molecular Foundry, Lawrence Berkeley National Laboratory, One Cyclotron Road, MS 67R6110, CA, USA
E-mail: yliu@lbl.gov
Fax: 01 510 4867413
Tel: 01 510 4866287

b Codexis Inc., 200 Penobsco, Redwood City, CA, USA

c University of California, Berkeley, CA, USA

Abstract

A face-to-face binding motif between dibenzylammonium ions and macrocycles containing 1,2,3-triazoles was established, which operates cooperatively to enhance the reactivity of 1,2,3-triazoles in an Arbuzov-type dealkylation reaction.

Graphical abstract: Enhancing the reactivity of 1,2,3-triazoles in “click” macrocycles by face-to-face dibenzylammonium ion binding

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Article information

DOI
https://doi.org/10.1039/B711505A
Article type
Communication
Submitted
30 Jul 2007
Accepted
15 Oct 2007
First published
23 Oct 2007

Chem. Commun., 2007, 4773-4775

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Enhancing the reactivity of 1,2,3-triazoles in “click” macrocycles by face-to-face dibenzylammonium ion binding

Y. Liu, X. Zhang, L. M. Klivansky and G. Koshkakaryan, Chem. Commun., 2007, 4773 DOI: 10.1039/B711505A

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