Issue 6, 2010
From the journal:

Chemical Communications

Molecular tectonics: crystal engineering of mixed valence Fe(ii)/Fe(iii) solid solutions†

Pierre Dechambenoit,a   Sylvie Ferlay,*a   Nathalie Kyritsakasa  and  Mir Wais Hosseini*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université de Strasbourg, Institut Le Bel, 4, rue Blaise Pascal, F-67000 Strasbourg, France

Abstract

Based on isostructurality between crystals formed upon combining the dicationic tecton 2 with either M3FeIII(CN)6 or M4FeII(CN)6 (M = Cs), a rare example of an H-bonded mixed valence Fe(II)–Fe(III) solid solution ((Cs223-[FeII(CN)6]2)0.83(23-[FeIII(CN)6]2)0.17)) and curious necklace-like composite crystals were generated.

Graphical abstract: Molecular tectonics: crystal engineering of mixed valence Fe(ii)/Fe(iii) solid solutions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B919478A
Article type
Communication
Submitted
18 Sep 2009
Accepted
13 Nov 2009
First published
30 Nov 2009

Chem. Commun., 2010,46, 868-870

Permissions

Request permissions

Molecular tectonics: crystal engineering of mixed valence Fe(II)/Fe(III) solid solutions

P. Dechambenoit, S. Ferlay, N. Kyritsakas and M. W. Hosseini, Chem. Commun., 2010, 46, 868 DOI: 10.1039/B919478A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements