Issue 28, 2010
From the journal:

Chemical Communications

Organolanthanoid-halide synthons—a new general route to monofunctionalized lanthanoid(ii) compounds?†

Michal Wiecko,*a   Glen B. Deacona  and  Peter C. Junk*a  

* Corresponding authors

a School of Chemistry, Monash University, Clayton, Victoria 3800, Australia
E-mail: peter.junk@sci.monash.edu.au, mwiecko@freenet.de
Fax: +61 (03)99054597
Tel: +61 (03)99054570

Abstract

New EuII and YbII complexes [Ln(Ph2pz)I(thf)4] were synthesized from the corresponding metals and 3,5-diphenylpyrazole (HPh2pz) using iodobenzene as oxidizing agent. In the absence of the pyrazole, the charge separated YbII/YbIII complex [{Yb(dme)4}{YbPh4(dme)}2] has been isolated.

Graphical abstract: Organolanthanoid-halide synthons—a new general route to monofunctionalized lanthanoid(ii) compounds?

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Article information

DOI
https://doi.org/10.1039/C0CC01317J
Article type
Communication
Submitted
10 May 2010
Accepted
02 Jun 2010
First published
16 Jun 2010

Chem. Commun., 2010,46, 5076-5078

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Organolanthanoid-halide synthons—a new general route to monofunctionalized lanthanoid(II) compounds?

M. Wiecko, G. B. Deacon and P. C. Junk, Chem. Commun., 2010, 46, 5076 DOI: 10.1039/C0CC01317J

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