Issue 104, 2005
From the journal:

CrystEngComm

Molecular tectonics: on the role of counter-ions in the dimensionality of silver coordination networks

David Pocic,a   Jean-Marc Planeix,a   Nathalie Kyritsakas,a   Abdelaziz Jouaitia  and  Mir Wais Hosseini*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université Louis Pasteur, F-67000 Strasbourg, France
E-mail: hosseini@chimie.u-strasbg.fr

Abstract

The role played by different anions (XF6− (X = P, As, Sb), BF4−) on the connectivity of coordination networks formed by a combination of different silver salts and an organic tecton based on piperazine bearing two pyridine units has been studied in the crystalline phase by X-ray diffraction on single crystal. All four weakly coordinating anions lead to the formation of analogous 2-D coordination networks. For the isostructural anions XF6− (X = P, As, Sb) the crystals are isomorphous.

Graphical abstract: Molecular tectonics: on the role of counter-ions in the dimensionality of silver coordination networks

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Article information

DOI
https://doi.org/10.1039/B513138N
Article type
Paper
Submitted
15 Sep 2005
Accepted
02 Nov 2005
First published
07 Nov 2005

CrystEngComm, 2005,7, 624-628

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Molecular tectonics: on the role of counter-ions in the dimensionality of silver coordination networks

D. Pocic, J. Planeix, N. Kyritsakas, A. Jouaiti and M. W. Hosseini, CrystEngComm, 2005, 7, 624 DOI: 10.1039/B513138N

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