Issue 4, 2009
From the journal:

CrystEngComm

The first observation of a Na2TiS2 related structure in a 2-D anionic manganese trimesate intercalated by cationic imidazole†,‡

Partha Mahataa  and  Srinivasan Natarajan*a  

* Corresponding authors

a Framework Solids Laboratory, Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore, India
E-mail: snatarajan@sscu.iisc.ernet.in
Fax: +91-80-2360-1310

Abstract

A hydrothermal reaction of Mn(OAc)2·4H2O, trimesic acid, imidazole, KOH and water at 75 °C for 24 h gave rise to a 2-D compound, [HImd][Mn(BTC)(H2O)] (Imd = imidazole; BTC = trimesate), with protonated imidazole molecules occupying the inter-lamellar space, and the structure resembles the classic inorganic compound, the sodium intercalated TiS2 (Na2TiS2).

Graphical abstract: The first observation of a Na2TiS2 related structure in a 2-D anionic manganese trimesate intercalated by cationic imidazole,

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Article information

DOI
https://doi.org/10.1039/B820248F
Article type
Communication
Submitted
12 Nov 2008
Accepted
17 Dec 2008
First published
27 Jan 2009

CrystEngComm, 2009,11, 560-563

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The first observation of a Na2TiS2 related structure in a 2-D anionic manganese trimesate intercalated by cationic imidazole,

P. Mahata and S. Natarajan, CrystEngComm, 2009, 11, 560 DOI: 10.1039/B820248F

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