Issue 19, 2005
From the journal:

Dalton Transactions

Primary amido substituted diborane(4) compounds and imidodiborate(4) anions

R. Angharad Baber,a   Jonathan P. H. Charmant,a   Alistair J. R. Cook,a   Natalie E. Farthing,a   Mairi F. Haddow,a   Nicholas C. Norman,*a   A. Guy Orpen,a   Christopher A. Russell*a  and  John M. Slatterya  

* Corresponding authors

a University of Bristol, School of Chemistry, Bristol, UK
E-mail: n.c.norman@bris.ac.uk, chris.russell@bris.ac.uk
Fax: +44 (0)117 929 0509
Tel: +44 (0)117 928 7577

Abstract

Treatment of the diborane(4) compound B2(NMe2)4 with aniline or 2,6-dimethylaniline results in the primary amido compounds B2(NHR)4 (R = Ph, 2,6-Me2C6H3); subsequent treatment with n-BuLi in toluene in each case affords the first examples of anionic imidodiborates namely Li4(thf)6B2(NPh)4 and Li4(thf)4B2(N-2,6-Me2C6H3)4; all complexes have been characterised crystallographically.

Graphical abstract: Primary amido substituted diborane(4) compounds and imidodiborate(4) anions

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Article information

DOI
https://doi.org/10.1039/B509653G
Article type
Communication
Submitted
08 Jul 2005
Accepted
22 Jul 2005
First published
23 Aug 2005

Dalton Trans., 2005, 3137-3139

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Primary amido substituted diborane(4) compounds and imidodiborate(4) anions

R. A. Baber, J. P. H. Charmant, A. J. R. Cook, N. E. Farthing, M. F. Haddow, N. C. Norman, A. G. Orpen, C. A. Russell and J. M. Slattery, Dalton Trans., 2005, 3137 DOI: 10.1039/B509653G

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