Issue 25, 2008
From the journal:

Dalton Transactions

Novel dinuclear and trinuclear palladium β-diiminate complexes containing amido–chloro double-bridges†

Alen Hadzovic,a   John Janetzkoa  and  Datong Song*a  

* Corresponding authors

a Davenport Chemical Research Laboratories, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada
E-mail: dsong@chem.utoronto.ca
Fax: +1 416 978 7013
Tel: +1 416 978 7014

Abstract

We report the formation of an unexpected trinuclear palladium β-diiminate complex from the decomposition of [Pd(Ph2nacnac)(Cl)(4-H2NC6H4-tBu)] (nacnac = β-diiminate derived from acetylacetone), the proposed reaction pathway, and the synthesis of the first dinuclear palladium complex with an amido–chloro double-bridge.

Graphical abstract: Novel dinuclear and trinuclear palladium β-diiminate complexes containing amido–chloro double-bridges

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Article information

DOI
https://doi.org/10.1039/B804792H
Article type
Communication
Submitted
25 Mar 2008
Accepted
17 Apr 2008
First published
16 May 2008

Dalton Trans., 2008, 3279-3281

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Novel dinuclear and trinuclear palladium β-diiminate complexes containing amido–chloro double-bridges

A. Hadzovic, J. Janetzko and D. Song, Dalton Trans., 2008, 3279 DOI: 10.1039/B804792H

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