Issue 8, 2010
From the journal:

Dalton Transactions

Molecular tectonics: formation and structural studies on a 2-D directional coordination network based on a non-centric metacyclophane based tecton and zinc cation†

Jérôme Ehrhart,a   Jean-Marc Planeix,*a   Nathalie Kyritsakas-Grubera  and  Mir Wais Hosseini*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination Organique (UMR CNRS 7140), Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal, France
E-mail: hosseini@chimie.u-strasbg.fr
Fax: 33 390241325
Tel: 33 390241323

Abstract

The combination of tectons based on the [1111]metacyclophane backbone blocked the 1,3-alternate conformation bearing two imidazoly or pyrazolyl groups located on the same side with metal halide complexes leads to the formation of either discrete metallmacrobicycles or infinite 1-D coordination networks. The same backbone bearing two sets of two different coordinating poles composed of two pyridyl and two pyrazolyl units, owing to its non-centrosymmetric nature, forms a directional 2-D network packed in an anti-parallel fashion.

Graphical abstract: Molecular tectonics: formation and structural studies on a 2-D directional coordination network based on a non-centric metacyclophane based tecton and zinc cation

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Article information

DOI
https://doi.org/10.1039/B917089H
Article type
Paper
Submitted
18 Aug 2009
Accepted
03 Dec 2009
First published
15 Jan 2010

Dalton Trans., 2010,39, 2137-2146

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Molecular tectonics: formation and structural studies on a 2-D directional coordination network based on a non-centric metacyclophane based tecton and zinc cation

J. Ehrhart, J. Planeix, N. Kyritsakas-Gruber and M. W. Hosseini, Dalton Trans., 2010, 39, 2137 DOI: 10.1039/B917089H

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