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J. Chem. Soc., Chem. Commun., 1995, 751 - 753, DOI: 10.1039/C39950000751
The self-assembly of branched [n]rotaxanes—the first step towards dendritic rotaxanes
David B. Amabilino, Peter R. Ashton, Martin B
lohradský, Françisco M. Raymo and J. Fraser Stoddart
The self-assembly, by means of a slippage procedure, of three novel rotaxanes incorporating, respectively, one, two and three bisparaphenylene-34-crown-10 macrocyclic components and a single branched component, consisting of three bipyridinium units attached covalently to a 1,3,5-trisubstituted benzene central core and each bearing at its other end a substituted tetraarylmethane blocking group, is described.
