Issue 3, 1996
From the journal:

Chemical Communications

1,2-Bis[2-(2,4,6-tri-tert-butylphenyl)phosphanediylmethyl]benzene, L: synthesis and structure of L, of the chelated complex [PdLCl2] and of a derived cyclometallated chiral complex

Abdelaziz Jouaiti,   Michel Geoffroy  and  Gérald Bernardinelli  

Abstract

The synthesis and crystal structure of 1,2-bis[2-(2,4,6-tri-tert-butylphenyl)phosphanediylmethyl]benzene, L, are reported as well as the preparation and conformation of the novel seven-membered ring complex [PdLCl2]; this complex reacts with alcohols (MeOH, EtOH) to give a chiral cyclometallated complex [rac(R)P, (R)C; (S)P, (S)C] where the metal is bound to both a phosphaalkene and a phosphite phosphorus atom.

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Article information

DOI
https://doi.org/10.1039/CC9960000437
Article type
Paper

Chem. Commun., 1996, 437-438

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1,2-Bis[2-(2,4,6-tri-tert-butylphenyl)phosphanediylmethyl]benzene, L: synthesis and structure of L, of the chelated complex [PdLCl2] and of a derived cyclometallated chiral complex

A. Jouaiti, M. Geoffroy and G. Bernardinelli, Chem. Commun., 1996, 437 DOI: 10.1039/CC9960000437

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