Issue 8, 1973
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Aspects of tautomerism. Part IV. A kinetic study of the dimerization reaction of pseudo-acid chlorides

M. Vivekananda Bhatt  and  Marayil Ravindranathan  

Abstract

The kinetics of dimerization of 4′-substituted- and unsubstituted o-benzoylbenzoyl chlorides, with iodide ion can be described by the expression, rate =k2[acid chloride][iodide]. The ρ value for the reaction in dimethylformamide solution is –0·38. The entropy of activation for the reaction is –34·2 cal mol–1 K–1 and the activation energy is 10·7 kcal mol–1. These results have been interpreted as evidence for the formation of pseudo-iodide in the rate-determining step and its fast decomposition to radicals which combine to give a mixture of stereoisomeric dilactones.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/P29730001158
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1973, 1158-1160

Permissions

Request permissions

Aspects of tautomerism. Part IV. A kinetic study of the dimerization reaction of pseudo-acid chlorides

M. V. Bhatt and M. Ravindranathan, J. Chem. Soc., Perkin Trans. 2, 1973, 1158 DOI: 10.1039/P29730001158

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements